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Obsidian as a Raw Material for Eco-Friendly Synthesis of Magnetic Zeolites
A sample of rhyolitic obsidian (OS) was used as raw material for zeolite synthesis by long (4 days) and fast (2 h)-aging hydrothermal processes. Zeolite synthesis was also performed by a fast (2 h) sonication method. The products were analysed by X-ray diffraction (XRD) and scanning electron microsc...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7603046/ https://www.ncbi.nlm.nih.gov/pubmed/33081399 http://dx.doi.org/10.3390/ma13204633 |
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author | Belviso, Claudia Peddis, Davide Varvaro, Gaspare Abdolrahimi, Maryam Reverberi, Andrea Pietro Cavalcante, Francesco |
author_facet | Belviso, Claudia Peddis, Davide Varvaro, Gaspare Abdolrahimi, Maryam Reverberi, Andrea Pietro Cavalcante, Francesco |
author_sort | Belviso, Claudia |
collection | PubMed |
description | A sample of rhyolitic obsidian (OS) was used as raw material for zeolite synthesis by long (4 days) and fast (2 h)-aging hydrothermal processes. Zeolite synthesis was also performed by a fast (2 h) sonication method. The products were analysed by X-ray diffraction (XRD) and scanning electron microscopy (SEM) both immediately after and 3 years after their formation in order to determine the stability of synthetic materials according to the method used. The results confirm zeolitization of obsidian both by long-aging conventional hydrothermal heating and fast hydrothermal process. However, the data highlight the efficiency of direct ultrasound energy in achieving more stable zeolite crystals over time. These results carried out using a natural source, follow those already obtained using wastes and pure sources as raw materials thus providing a definitive validation of the different mechanisms controlling zeolite formation according to the process used. Moreover, the results confirm the effectiveness of ultrasonic energy in the formation of zeolites that are more stable over time. Due to the chemical composition of the obsidian precursor, all synthetic zeolites show good magnetic properties (i.e., saturation magnetization), in view to potential magnetic separation. |
format | Online Article Text |
id | pubmed-7603046 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-76030462020-11-01 Obsidian as a Raw Material for Eco-Friendly Synthesis of Magnetic Zeolites Belviso, Claudia Peddis, Davide Varvaro, Gaspare Abdolrahimi, Maryam Reverberi, Andrea Pietro Cavalcante, Francesco Materials (Basel) Article A sample of rhyolitic obsidian (OS) was used as raw material for zeolite synthesis by long (4 days) and fast (2 h)-aging hydrothermal processes. Zeolite synthesis was also performed by a fast (2 h) sonication method. The products were analysed by X-ray diffraction (XRD) and scanning electron microscopy (SEM) both immediately after and 3 years after their formation in order to determine the stability of synthetic materials according to the method used. The results confirm zeolitization of obsidian both by long-aging conventional hydrothermal heating and fast hydrothermal process. However, the data highlight the efficiency of direct ultrasound energy in achieving more stable zeolite crystals over time. These results carried out using a natural source, follow those already obtained using wastes and pure sources as raw materials thus providing a definitive validation of the different mechanisms controlling zeolite formation according to the process used. Moreover, the results confirm the effectiveness of ultrasonic energy in the formation of zeolites that are more stable over time. Due to the chemical composition of the obsidian precursor, all synthetic zeolites show good magnetic properties (i.e., saturation magnetization), in view to potential magnetic separation. MDPI 2020-10-16 /pmc/articles/PMC7603046/ /pubmed/33081399 http://dx.doi.org/10.3390/ma13204633 Text en © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Belviso, Claudia Peddis, Davide Varvaro, Gaspare Abdolrahimi, Maryam Reverberi, Andrea Pietro Cavalcante, Francesco Obsidian as a Raw Material for Eco-Friendly Synthesis of Magnetic Zeolites |
title | Obsidian as a Raw Material for Eco-Friendly Synthesis of Magnetic Zeolites |
title_full | Obsidian as a Raw Material for Eco-Friendly Synthesis of Magnetic Zeolites |
title_fullStr | Obsidian as a Raw Material for Eco-Friendly Synthesis of Magnetic Zeolites |
title_full_unstemmed | Obsidian as a Raw Material for Eco-Friendly Synthesis of Magnetic Zeolites |
title_short | Obsidian as a Raw Material for Eco-Friendly Synthesis of Magnetic Zeolites |
title_sort | obsidian as a raw material for eco-friendly synthesis of magnetic zeolites |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7603046/ https://www.ncbi.nlm.nih.gov/pubmed/33081399 http://dx.doi.org/10.3390/ma13204633 |
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