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Mechanistic Studies for Palladium Catalyzed Copolymerization of Ethylene with Vinyl Ethers
The mechanism of ethylene with vinyl ether (VE, CH(2)=CHOEt) copolymerization catalyzed by phosphine-sulfonate palladium complex (A) was investigated by density functional theory (DFT) calculation. On achieving an agreement between theory and experiment, it is found that the favorable 1,2-selective...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7603233/ https://www.ncbi.nlm.nih.gov/pubmed/33086515 http://dx.doi.org/10.3390/polym12102401 |