Cargando…

Copper(I)-catalyzed asymmetric 1,6-conjugate allylation

Catalytic asymmetric conjugate allylation of unsaturated carbonyl compounds is usually difficult to achieve, as 1,2-addition proceeds dominantly and high asymmetric induction is a challenging task. Herein, we disclose a copper(I)-NHC complex catalyzed asymmetric 1,6-conjugate allylation of 2,2-dimet...

Descripción completa

Detalles Bibliográficos
Autores principales:	Shi, Chang-Yun, Pan, Zhi-Zhou, Tian, Ping, Yin, Liang
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Nature Publishing Group UK 2020
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7603333/ https://www.ncbi.nlm.nih.gov/pubmed/33127903 http://dx.doi.org/10.1038/s41467-020-19293-9

Ejemplares similares

Desymmetrization of meso-Dibromocycloalkenes through Copper(I)-Catalyzed Asymmetric Allylic Substitution with Organolithium Reagents
por: Goh, Shermin S., et al.
Publicado: (2018)

Copper-catalyzed asymmetric allylic alkylation of racemic inert cyclic allylic ethers under batch and flow conditions
por: Li, Jun, et al.
Publicado: (2023)

Copper-Catalyzed Enantioselective Borylative Allyl–Allyl Coupling of Allenes and Allylic gem-Dichlorides
por: Piñeiro-Suárez, Martín, et al.
Publicado: (2023)

Copper(I)-catalyzed asymmetric alkylation of α-imino-esters
por: Liu, Zong-Ci, et al.
Publicado: (2023)

Catalytic enantioselective 1,6-conjugate additions of propargyl and allyl groups
por: Meng, Fanke, et al.
Publicado: (2016)

Nickel-catalyzed asymmetric reductive aryl-allylation of unactivated alkenes
por: Lin, Zhiyang, et al.
Publicado: (2021)

Asymmetric Synthesis of Nortropanes via Rh-Catalyzed Allylic Arylation
por: Zhang, Yan, et al.
Publicado: (2022)

Enantioselective and site-specific copper-catalyzed reductive allyl–allyl cross-coupling of allenes
por: Xu, Guoxing, et al.
Publicado: (2018)

Copper(I)-catalyzed asymmetric 1,3-dipolar cycloaddition of 1,3-enynes and azomethine ylides
por: Wang, Bo-Ran, et al.
Publicado: (2023)

Pd-catalyzed asymmetric allylic alkylations via C–H activation of N-allyl imines with glycinates
por: Trost, Barry M., et al.
Publicado: (2017)

Stereodivergent synthesis via iridium-catalyzed asymmetric double allylic alkylation of cyanoacetate
por: Shen, Chong, et al.
Publicado: (2021)

Copper-catalyzed asymmetric conjugate addition of organometallic reagents to extended Michael acceptors
por: Schmid, Thibault E, et al.
Publicado: (2015)

Tungsten-Catalyzed Asymmetric Epoxidation of Allylic and Homoallylic Alcohols with Hydrogen Peroxide
por: Wang, Chuan, et al.
Publicado: (2014)

Palladium-catalyzed asymmetric allylic alkylation (AAA) with alkyl sulfones as nucleophiles
por: Trost, Barry M., et al.
Publicado: (2021)

Enantioselective construction of C-chiral allylic sulfilimines via the iridium-catalyzed allylic amination with S,S-diphenylsulfilimine: asymmetric synthesis of primary allylic amines
por: Grange, Rebecca L., et al.
Publicado: (2015)

Effective synthesis of bicyclodienes via palladium-catalyzed asymmetric allylic alkylation and ruthenium-catalyzed cycloisomerization
por: HAVARE, Nizam
Publicado: (2020)

Synthesis of chiral anti-1,2-diamine derivatives through copper(I)-catalyzed asymmetric α-addition of ketimines to aldimines
por: Gan, Xu-Cheng, et al.
Publicado: (2020)

Palladium-Catalyzed Decarboxylative Asymmetric Allylic Alkylation of Thietane 1,1-Dioxides
por: Laidlaw, Gillian, et al.
Publicado: (2021)

Palladium-catalyzed asymmetric allylic 4-pyridinylation via electroreductive substitution reaction
por: Ding, Weijie, et al.
Publicado: (2022)

Enantio‐ and Diastereoselective Copper‐Catalyzed Allylboration of Alkynes with Allylic gem‐Dichlorides
por: Chaves‐Pouso, Andrea, et al.
Publicado: (2022)

Copper-catalysed asymmetric allylic alkylation of alkylzirconocenes to racemic 3,6-dihydro-2H-pyrans
por: Rideau, Emeline, et al.
Publicado: (2015)

Copper(I)-catalyzed asymmetric decarboxylative Mannich reaction enabled by acidic activation of 2H-azirines
por: Zhang, Hai-Jun, et al.
Publicado: (2019)

Asymmetric synthesis of 1,2-fluorohydrin: iridium catalyzed hydrogenation of fluorinated allylic alcohol
por: Ponra, Sudipta, et al.
Publicado: (2020)

Enantioselective and Regiodivergent Copper-Catalyzed Electrophilic Arylation of Allylic Amides with Diaryliodonium Salts
por: Cahard, Elise, et al.
Publicado: (2015)

Nickel-catalyzed direct stereoselective α-allylation of ketones with non-conjugated dienes
por: Cao, Yi-Xuan, et al.
Publicado: (2023)

Copper-Catalyzed Asymmetric Sulfonylative Desymmetrization of Glycerol
por: Yamamoto, Kosuke, et al.
Publicado: (2022)

Development of Immobilized Carreira (Phosphoramidite, Olefin) Ligands and Application in Iridium-Catalyzed Asymmetric Allylic Amination
por: Zhou, Leijie, et al.
Publicado: (2023)

Influence of Achiral Phosphine Ligands on a Synergistic Organo‐ and Palladium‐Catalyzed Asymmetric Allylic Alkylation
por: McLeod, David, et al.
Publicado: (2022)

Palladium-Catalyzed Cascade Wacker/Allylation Sequence with Allylic Alcohols Leading to Allylated Dihydropyrones
por: Huang, Wen-Yu, et al.
Publicado: (2017)

Gold(I)‐Catalyzed Nucleophilic Allylation of Azinium Ions with Allylboronates
por: O'Brien, Luke, et al.
Publicado: (2022)

Copper-Catalyzed Oxidative Dehydrogenative Carboxylation of Unactivated Alkanes to Allylic Esters via Alkenes
por: Tran, Ba L., et al.
Publicado: (2014)

Recent advances in copper-catalyzed asymmetric coupling reactions
por: Zhou, Fengtao, et al.
Publicado: (2015)

Copper-catalyzed asymmetric methylation of fluoroalkylated pyruvates with dimethylzinc
por: Aikawa, Kohsuke, et al.
Publicado: (2018)

Dehydration in water: frustrated Lewis pairs directly catalyzed allylization of electron-rich arenes and allyl alcohols
por: Zhang, Hua, et al.
Publicado: (2020)

Platinum-Catalyzed Allylation of 2,3-Disubstituted Indoles with Allylic Acetates
por: Peng, Bai-Jing, et al.
Publicado: (2017)

Copper-Catalyzed Asymmetric Dearomative [3+2] Cycloaddition of Nitroheteroarenes with Azomethines
por: Chen, Yan, et al.
Publicado: (2023)

Asymmetric synthesis of multifunctional aryl allyl ethers by nucleophilic catalysis
por: Zhao, Shuai, et al.
Publicado: (2019)

Asymmetric Vinylogous Aldol-type Reactions of Aldehydes with Allyl Phosphonate and Sulfone
por: Yue, Wen-Jun, et al.
Publicado: (2019)

Diastereodivergent chiral aldehyde catalysis for asymmetric 1,6-conjugated addition and Mannich reactions
por: Wen, Wei, et al.
Publicado: (2020)

Ni-catalyzed asymmetric hydrophosphinylation of conjugated enynes and mechanistic studies
por: Zhang, Ya-Qian, et al.
Publicado: (2022)

Cannot write session to /tmp/vufind_sessions/sess_ql6ttbm1ha563evds7vbj502lg