Cargando…
C–C bond activation enabled by dyotropic rearrangement of Pd(IV) species
The weak carbon–metal bond combined with the kinetic inertness of carbon–carbon bond renders the metal catalyzed C–C bond activation to be highly challenging. Most of the reported C–C bond activation methodologies involve the strain-releasing cleavage of small rings to compensate the unfavorable kin...
Autores principales: | Cao, Jian, Wu, Hua, Wang, Qian, Zhu, Jieping |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
2021
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7611116/ https://www.ncbi.nlm.nih.gov/pubmed/34031566 http://dx.doi.org/10.1038/s41557-021-00698-y |
Ejemplares similares
-
Synthesis of Hydrofluoroolefin‐Based Iodonium Reagent via Dyotropic Rearrangement and Its Utilization in Fluoroalkylation
por: Csenki, János T., et al.
Publicado: (2022) -
Stereospecific
Ring Contraction of Bromocycloheptenes
through Dyotropic Rearrangements via Nonclassical Carbocation–Anion
Pairs
por: Goh, Shermin S., et al.
Publicado: (2018) -
Carbon–hydrogen (C–H) bond activation at Pd(IV): a Frontier in C–H functionalization catalysis
por: Topczewski, Joseph J., et al.
Publicado: (2015) -
Functionalization of remote C(sp(3))-H bonds enabled by copper-catalyzed coupling of O-acyloximes with terminal alkynes
por: Li, Zhaodong, et al.
Publicado: (2020) -
Natural Product Synthesis Enabled by Domino Processes
Incorporating a 1,2-Rearrangement Step
por: Delayre, Bastien, et al.
Publicado: (2021)