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Chain propagation determines the chemo- and regioselectivity of alkyl radical additions to C–O vs. C–C double bonds
Investigations into the selectivity of intermolecular alkyl radical additions to C–O- vs. C–C-double bonds in α,β-unsaturated carbonyl compounds are described. Therefore, a photoredox-initiated radical chain reaction is explored, where the activation of the carbonyl-group through an in situ generate...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7640737/ https://www.ncbi.nlm.nih.gov/pubmed/33209246 http://dx.doi.org/10.1039/c9sc04846d |