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Cardanol /SiO(2) Nanocomposites for Inhibition of Formation Damage by Asphaltene Precipitation/Deposition in Light Crude Oil Reservoirs. Part II: Nanocomposite Evaluation and Coreflooding Test
[Image: see text] This study aims to evaluate the behavior of Cardanol/SiO(2) nanocomposites in the inhibition of the asphaltene damage based on the coreflooding test at reservoir conditions. The nanocomposite design was performed in Part I (https://doi.org/10.1021/acs.energyfuels.0c01114), leading...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2020
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7643095/ https://www.ncbi.nlm.nih.gov/pubmed/33163763 http://dx.doi.org/10.1021/acsomega.0c02722 |
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author | López, Daniel Jaramillo, Juan E. Lucas, Elizabete F. Riazi, Masoud Lopera, Sergio H. Franco, Camilo A. Cortés, Farid B. |
author_facet | López, Daniel Jaramillo, Juan E. Lucas, Elizabete F. Riazi, Masoud Lopera, Sergio H. Franco, Camilo A. Cortés, Farid B. |
author_sort | López, Daniel |
collection | PubMed |
description | [Image: see text] This study aims to evaluate the behavior of Cardanol/SiO(2) nanocomposites in the inhibition of the asphaltene damage based on the coreflooding test at reservoir conditions. The nanocomposite design was performed in Part I (https://doi.org/10.1021/acs.energyfuels.0c01114), leading to SiO(2) nanoparticles functionalized with different mass fractions of cardanol on the surface of 5 (5CSN), 7 (7CSN), and 9% (9CSN). In this part of the study, the nanocomposite/reservoir fluid interactions were evaluated through interfacial tension measurements and nanocomposite/rock surface interactions using water imbibition and contact angle measurements. Results showed that the designed nanocomposite leads to a reduction of interfacial tension of 82.6, 61.7, and 51.4% for 5CSN, 7CSN, and 9CSN regarding silica support (SN). Whereas, the reduction of the Si–OH functional groups from SiO(2) nanoparticles due to the increase of the cardanol content affects the effectiveness of the wettability alteration for 7CSN and 9CSN. Nevertheless, when 5CSN is evaluated, the system is altered from an oil-wet to a mixed-wet state. Coreflooding tests at reservoir conditions were performed to evaluate the oil recovery after asphaltene damage, after damage removal and nanofluid injection, and after induction of a second asphaltene damage to check inhibition. Results show that the selected nanocomposites at a dosage of 300 mg·L(–1) enhance the oil recovery in comparison with the baseline conditions via the reduction of the interfacial/surface forces at the pore scale and wettability alteration. It is worth to remark that this improvement remains after the second asphaltene damage induction, which proves the high inhibitory capacity of the designed nanocomposite for the asphaltene precipitation/deposition. Also, the use of the nanocomposites favors the oil recovery more than 50% compared to the asphaltene damage scenario. |
format | Online Article Text |
id | pubmed-7643095 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | American Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-76430952020-11-06 Cardanol /SiO(2) Nanocomposites for Inhibition of Formation Damage by Asphaltene Precipitation/Deposition in Light Crude Oil Reservoirs. Part II: Nanocomposite Evaluation and Coreflooding Test López, Daniel Jaramillo, Juan E. Lucas, Elizabete F. Riazi, Masoud Lopera, Sergio H. Franco, Camilo A. Cortés, Farid B. ACS Omega [Image: see text] This study aims to evaluate the behavior of Cardanol/SiO(2) nanocomposites in the inhibition of the asphaltene damage based on the coreflooding test at reservoir conditions. The nanocomposite design was performed in Part I (https://doi.org/10.1021/acs.energyfuels.0c01114), leading to SiO(2) nanoparticles functionalized with different mass fractions of cardanol on the surface of 5 (5CSN), 7 (7CSN), and 9% (9CSN). In this part of the study, the nanocomposite/reservoir fluid interactions were evaluated through interfacial tension measurements and nanocomposite/rock surface interactions using water imbibition and contact angle measurements. Results showed that the designed nanocomposite leads to a reduction of interfacial tension of 82.6, 61.7, and 51.4% for 5CSN, 7CSN, and 9CSN regarding silica support (SN). Whereas, the reduction of the Si–OH functional groups from SiO(2) nanoparticles due to the increase of the cardanol content affects the effectiveness of the wettability alteration for 7CSN and 9CSN. Nevertheless, when 5CSN is evaluated, the system is altered from an oil-wet to a mixed-wet state. Coreflooding tests at reservoir conditions were performed to evaluate the oil recovery after asphaltene damage, after damage removal and nanofluid injection, and after induction of a second asphaltene damage to check inhibition. Results show that the selected nanocomposites at a dosage of 300 mg·L(–1) enhance the oil recovery in comparison with the baseline conditions via the reduction of the interfacial/surface forces at the pore scale and wettability alteration. It is worth to remark that this improvement remains after the second asphaltene damage induction, which proves the high inhibitory capacity of the designed nanocomposite for the asphaltene precipitation/deposition. Also, the use of the nanocomposites favors the oil recovery more than 50% compared to the asphaltene damage scenario. American Chemical Society 2020-10-23 /pmc/articles/PMC7643095/ /pubmed/33163763 http://dx.doi.org/10.1021/acsomega.0c02722 Text en © 2020 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes. |
spellingShingle | López, Daniel Jaramillo, Juan E. Lucas, Elizabete F. Riazi, Masoud Lopera, Sergio H. Franco, Camilo A. Cortés, Farid B. Cardanol /SiO(2) Nanocomposites for Inhibition of Formation Damage by Asphaltene Precipitation/Deposition in Light Crude Oil Reservoirs. Part II: Nanocomposite Evaluation and Coreflooding Test |
title | Cardanol /SiO(2) Nanocomposites for Inhibition
of Formation Damage by Asphaltene Precipitation/Deposition in Light
Crude Oil Reservoirs. Part II: Nanocomposite Evaluation and Coreflooding
Test |
title_full | Cardanol /SiO(2) Nanocomposites for Inhibition
of Formation Damage by Asphaltene Precipitation/Deposition in Light
Crude Oil Reservoirs. Part II: Nanocomposite Evaluation and Coreflooding
Test |
title_fullStr | Cardanol /SiO(2) Nanocomposites for Inhibition
of Formation Damage by Asphaltene Precipitation/Deposition in Light
Crude Oil Reservoirs. Part II: Nanocomposite Evaluation and Coreflooding
Test |
title_full_unstemmed | Cardanol /SiO(2) Nanocomposites for Inhibition
of Formation Damage by Asphaltene Precipitation/Deposition in Light
Crude Oil Reservoirs. Part II: Nanocomposite Evaluation and Coreflooding
Test |
title_short | Cardanol /SiO(2) Nanocomposites for Inhibition
of Formation Damage by Asphaltene Precipitation/Deposition in Light
Crude Oil Reservoirs. Part II: Nanocomposite Evaluation and Coreflooding
Test |
title_sort | cardanol /sio(2) nanocomposites for inhibition
of formation damage by asphaltene precipitation/deposition in light
crude oil reservoirs. part ii: nanocomposite evaluation and coreflooding
test |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7643095/ https://www.ncbi.nlm.nih.gov/pubmed/33163763 http://dx.doi.org/10.1021/acsomega.0c02722 |
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