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Properties and Composition of Products from Hydrotreating of Straight-Run Gas Oil and Its Mixtures with Light Cycle Oil Over Sulfidic Ni-Mo/Al(2)O(3) Catalyst
[Image: see text] Straight-run gas oil (SRGO) and its mixtures with 5, 10, 15, and 20 wt % light cycle oil (LCO) from fluid catalytic cracking (FCC) were hydrotreated on a commercial NiMo/Al(2)O(3) catalyst in a laboratory tubular reactor with the cocurrent flow of the raw material and hydrogen. The...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2020
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7643143/ https://www.ncbi.nlm.nih.gov/pubmed/33163775 http://dx.doi.org/10.1021/acsomega.0c03259 |
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author | Tomášek, Josef Matějovský, Lukáš Lamblová, Martina Blažek, Josef |
author_facet | Tomášek, Josef Matějovský, Lukáš Lamblová, Martina Blažek, Josef |
author_sort | Tomášek, Josef |
collection | PubMed |
description | [Image: see text] Straight-run gas oil (SRGO) and its mixtures with 5, 10, 15, and 20 wt % light cycle oil (LCO) from fluid catalytic cracking (FCC) were hydrotreated on a commercial NiMo/Al(2)O(3) catalyst in a laboratory tubular reactor with the cocurrent flow of the raw material and hydrogen. The hydrotreating of the raw material was undertaken at a temperature of 350 °C, a pressure of 4 MPa, a weight hourly space velocity of ca 1.0 h(–1), and a hydrogen-to-raw-material ratio of 240 m(3)·m(–3). The LCO had a high density due to the high content of bicyclic aromatics and the high content of sulfur species, which are difficult to desulfurize. Therefore, increasing the content of the LCO in the raw material resulted in increasing the density and increasing the content of the sulfur and polycyclic aromatics in the hydrotreated products. Only the products prepared from the raw material with LCO content up to 10 wt % fulfilled the density requirement of EN 590. To improve the product density, the products prepared from the raw material containing 15 wt % LCO were blended with refined kerosene. The addition of the kerosene decreased the density of the mixtures prepared, but the cold filter plugging point (CFPP) of the mixtures was only lowered by about 1–2 °C. It was necessary to add a depressant in an amount of 600 mg·kg(–1) to achieve a cold filter plugging point of −20 °C. Some refined products were blended with desulfurized heavy naphtha from the FCC. The addition of the heavy naphtha was mainly limited by its high density. Up to 10 wt % heavy naphtha could be added to the product obtained by hydrotreating the raw material containing 10 wt % LCO. More than 15 wt % heavy naphtha could be added to the mixture of the hydrotreated product and 20 wt % kerosene. |
format | Online Article Text |
id | pubmed-7643143 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | American Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-76431432020-11-06 Properties and Composition of Products from Hydrotreating of Straight-Run Gas Oil and Its Mixtures with Light Cycle Oil Over Sulfidic Ni-Mo/Al(2)O(3) Catalyst Tomášek, Josef Matějovský, Lukáš Lamblová, Martina Blažek, Josef ACS Omega [Image: see text] Straight-run gas oil (SRGO) and its mixtures with 5, 10, 15, and 20 wt % light cycle oil (LCO) from fluid catalytic cracking (FCC) were hydrotreated on a commercial NiMo/Al(2)O(3) catalyst in a laboratory tubular reactor with the cocurrent flow of the raw material and hydrogen. The hydrotreating of the raw material was undertaken at a temperature of 350 °C, a pressure of 4 MPa, a weight hourly space velocity of ca 1.0 h(–1), and a hydrogen-to-raw-material ratio of 240 m(3)·m(–3). The LCO had a high density due to the high content of bicyclic aromatics and the high content of sulfur species, which are difficult to desulfurize. Therefore, increasing the content of the LCO in the raw material resulted in increasing the density and increasing the content of the sulfur and polycyclic aromatics in the hydrotreated products. Only the products prepared from the raw material with LCO content up to 10 wt % fulfilled the density requirement of EN 590. To improve the product density, the products prepared from the raw material containing 15 wt % LCO were blended with refined kerosene. The addition of the kerosene decreased the density of the mixtures prepared, but the cold filter plugging point (CFPP) of the mixtures was only lowered by about 1–2 °C. It was necessary to add a depressant in an amount of 600 mg·kg(–1) to achieve a cold filter plugging point of −20 °C. Some refined products were blended with desulfurized heavy naphtha from the FCC. The addition of the heavy naphtha was mainly limited by its high density. Up to 10 wt % heavy naphtha could be added to the product obtained by hydrotreating the raw material containing 10 wt % LCO. More than 15 wt % heavy naphtha could be added to the mixture of the hydrotreated product and 20 wt % kerosene. American Chemical Society 2020-10-21 /pmc/articles/PMC7643143/ /pubmed/33163775 http://dx.doi.org/10.1021/acsomega.0c03259 Text en © 2020 American Chemical Society This is an open access article published under a Creative Commons Non-Commercial No Derivative Works (CC-BY-NC-ND) Attribution License (http://pubs.acs.org/page/policy/authorchoice_ccbyncnd_termsofuse.html) , which permits copying and redistribution of the article, and creation of adaptations, all for non-commercial purposes. |
spellingShingle | Tomášek, Josef Matějovský, Lukáš Lamblová, Martina Blažek, Josef Properties and Composition of Products from Hydrotreating of Straight-Run Gas Oil and Its Mixtures with Light Cycle Oil Over Sulfidic Ni-Mo/Al(2)O(3) Catalyst |
title | Properties and Composition of Products from Hydrotreating
of Straight-Run Gas Oil and Its Mixtures with Light Cycle Oil Over
Sulfidic Ni-Mo/Al(2)O(3) Catalyst |
title_full | Properties and Composition of Products from Hydrotreating
of Straight-Run Gas Oil and Its Mixtures with Light Cycle Oil Over
Sulfidic Ni-Mo/Al(2)O(3) Catalyst |
title_fullStr | Properties and Composition of Products from Hydrotreating
of Straight-Run Gas Oil and Its Mixtures with Light Cycle Oil Over
Sulfidic Ni-Mo/Al(2)O(3) Catalyst |
title_full_unstemmed | Properties and Composition of Products from Hydrotreating
of Straight-Run Gas Oil and Its Mixtures with Light Cycle Oil Over
Sulfidic Ni-Mo/Al(2)O(3) Catalyst |
title_short | Properties and Composition of Products from Hydrotreating
of Straight-Run Gas Oil and Its Mixtures with Light Cycle Oil Over
Sulfidic Ni-Mo/Al(2)O(3) Catalyst |
title_sort | properties and composition of products from hydrotreating
of straight-run gas oil and its mixtures with light cycle oil over
sulfidic ni-mo/al(2)o(3) catalyst |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7643143/ https://www.ncbi.nlm.nih.gov/pubmed/33163775 http://dx.doi.org/10.1021/acsomega.0c03259 |
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