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Photocatalytic Activity of Graphene Oxide/Zinc Oxide Nanocomposites with Embedded Metal Nanoparticles for the Degradation of Organic Dyes

[Image: see text] Nanocomposite materials based on metal nanoparticles and graphene oxide (GO) have gained increasing attention for their wide range of potential applications in various materials science fields. In this study, an efficient photocatalyst based on GO/ZnO nanocomposites with embedded m...

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Autores principales: Al-Rawashdeh, Nathir A. F., Allabadi, Odai, Aljarrah, Mohannad T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7643185/
https://www.ncbi.nlm.nih.gov/pubmed/33163787
http://dx.doi.org/10.1021/acsomega.0c03608
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author Al-Rawashdeh, Nathir A. F.
Allabadi, Odai
Aljarrah, Mohannad T.
author_facet Al-Rawashdeh, Nathir A. F.
Allabadi, Odai
Aljarrah, Mohannad T.
author_sort Al-Rawashdeh, Nathir A. F.
collection PubMed
description [Image: see text] Nanocomposite materials based on metal nanoparticles and graphene oxide (GO) have gained increasing attention for their wide range of potential applications in various materials science fields. In this study, an efficient photocatalyst based on GO/ZnO nanocomposites with embedded metal nanoparticles was successfully synthesized via a simple one-pot method. The synthesized nanocomposites were characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), and Fourier transform infrared (FTIR) spectroscopy. The photocatalytic activity of the synthesized nanocomposites was tested in the degradation of methylene blue (MB) dyes, as a model of water pollutants. A catalytic activity of 84% was achieved using a nanocomposite with a percentage of 3.125% GO, after 90 min sunlight irradiation. Furthermore, embedded copper and silver nanoparticles were used as dopants to study their effects on the activity of the photocatalyst. The GO–ZnO–Cu nanocomposite showed that the activity toward MB degradation was decreased by 50%, while a significant increase in the activity of MB degradation was achieved by the GO–ZnO–Ag nanocomposite. The removal efficiency of MB by the GO–ZnO–Ag nanocomposite reached 100% after 40 min of sunlight irradiation. Thus, the GO–ZnO–Ag nanocomposite has the potential to be an efficient adaptable photocatalyst for the photodegradation of organic dyes in industrial wastewater.
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spelling pubmed-76431852020-11-06 Photocatalytic Activity of Graphene Oxide/Zinc Oxide Nanocomposites with Embedded Metal Nanoparticles for the Degradation of Organic Dyes Al-Rawashdeh, Nathir A. F. Allabadi, Odai Aljarrah, Mohannad T. ACS Omega [Image: see text] Nanocomposite materials based on metal nanoparticles and graphene oxide (GO) have gained increasing attention for their wide range of potential applications in various materials science fields. In this study, an efficient photocatalyst based on GO/ZnO nanocomposites with embedded metal nanoparticles was successfully synthesized via a simple one-pot method. The synthesized nanocomposites were characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), and Fourier transform infrared (FTIR) spectroscopy. The photocatalytic activity of the synthesized nanocomposites was tested in the degradation of methylene blue (MB) dyes, as a model of water pollutants. A catalytic activity of 84% was achieved using a nanocomposite with a percentage of 3.125% GO, after 90 min sunlight irradiation. Furthermore, embedded copper and silver nanoparticles were used as dopants to study their effects on the activity of the photocatalyst. The GO–ZnO–Cu nanocomposite showed that the activity toward MB degradation was decreased by 50%, while a significant increase in the activity of MB degradation was achieved by the GO–ZnO–Ag nanocomposite. The removal efficiency of MB by the GO–ZnO–Ag nanocomposite reached 100% after 40 min of sunlight irradiation. Thus, the GO–ZnO–Ag nanocomposite has the potential to be an efficient adaptable photocatalyst for the photodegradation of organic dyes in industrial wastewater. American Chemical Society 2020-10-23 /pmc/articles/PMC7643185/ /pubmed/33163787 http://dx.doi.org/10.1021/acsomega.0c03608 Text en © 2020 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Al-Rawashdeh, Nathir A. F.
Allabadi, Odai
Aljarrah, Mohannad T.
Photocatalytic Activity of Graphene Oxide/Zinc Oxide Nanocomposites with Embedded Metal Nanoparticles for the Degradation of Organic Dyes
title Photocatalytic Activity of Graphene Oxide/Zinc Oxide Nanocomposites with Embedded Metal Nanoparticles for the Degradation of Organic Dyes
title_full Photocatalytic Activity of Graphene Oxide/Zinc Oxide Nanocomposites with Embedded Metal Nanoparticles for the Degradation of Organic Dyes
title_fullStr Photocatalytic Activity of Graphene Oxide/Zinc Oxide Nanocomposites with Embedded Metal Nanoparticles for the Degradation of Organic Dyes
title_full_unstemmed Photocatalytic Activity of Graphene Oxide/Zinc Oxide Nanocomposites with Embedded Metal Nanoparticles for the Degradation of Organic Dyes
title_short Photocatalytic Activity of Graphene Oxide/Zinc Oxide Nanocomposites with Embedded Metal Nanoparticles for the Degradation of Organic Dyes
title_sort photocatalytic activity of graphene oxide/zinc oxide nanocomposites with embedded metal nanoparticles for the degradation of organic dyes
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7643185/
https://www.ncbi.nlm.nih.gov/pubmed/33163787
http://dx.doi.org/10.1021/acsomega.0c03608
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