Cargando…
Lu-atom-ordered oxonitridoaluminosilicate Ba(0.9)Ce(0.1)LuAl(0.2)Si(3.8)N(6.9)O(0.1)
A single crystal of Ba(0.9)Ce(0.1)LuAl(0.2)Si(3.8)N(6.9)O(0.1) (barium cerium lutetium aluminosilicate nitride oxide) was obtained by heating a mixed powder of Ba(3)N(2), Si(3)N(4), Al, Lu(2)O(3), and CeO(2) at 2173 K for 1 h under N(2) gas at 0.85 MPa. X-ray single-crystal structure analysis reveal...
Autores principales: | , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2020
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7643228/ https://www.ncbi.nlm.nih.gov/pubmed/33209337 http://dx.doi.org/10.1107/S2056989020013158 |
_version_ | 1783606238561435648 |
---|---|
author | Simura, Rayko Yamane, Hisanori |
author_facet | Simura, Rayko Yamane, Hisanori |
author_sort | Simura, Rayko |
collection | PubMed |
description | A single crystal of Ba(0.9)Ce(0.1)LuAl(0.2)Si(3.8)N(6.9)O(0.1) (barium cerium lutetium aluminosilicate nitride oxide) was obtained by heating a mixed powder of Ba(3)N(2), Si(3)N(4), Al, Lu(2)O(3), and CeO(2) at 2173 K for 1 h under N(2) gas at 0.85 MPa. X-ray single-crystal structure analysis revealed that the title oxynitride is hexagonal (lattice constants: a = 6.0378 (5) Å, c = 9.8133 (9) Å; space group: P6(3) mc) and isostructural with BaYbSi(4)N(7). (Ba,Ce) and Lu atoms occupy twelvefold and sixfold coordination sites, respectively. |
format | Online Article Text |
id | pubmed-7643228 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-76432282020-11-17 Lu-atom-ordered oxonitridoaluminosilicate Ba(0.9)Ce(0.1)LuAl(0.2)Si(3.8)N(6.9)O(0.1) Simura, Rayko Yamane, Hisanori Acta Crystallogr E Crystallogr Commun Research Communications A single crystal of Ba(0.9)Ce(0.1)LuAl(0.2)Si(3.8)N(6.9)O(0.1) (barium cerium lutetium aluminosilicate nitride oxide) was obtained by heating a mixed powder of Ba(3)N(2), Si(3)N(4), Al, Lu(2)O(3), and CeO(2) at 2173 K for 1 h under N(2) gas at 0.85 MPa. X-ray single-crystal structure analysis revealed that the title oxynitride is hexagonal (lattice constants: a = 6.0378 (5) Å, c = 9.8133 (9) Å; space group: P6(3) mc) and isostructural with BaYbSi(4)N(7). (Ba,Ce) and Lu atoms occupy twelvefold and sixfold coordination sites, respectively. International Union of Crystallography 2020-10-06 /pmc/articles/PMC7643228/ /pubmed/33209337 http://dx.doi.org/10.1107/S2056989020013158 Text en © Simura and Yamane 2020 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/ |
spellingShingle | Research Communications Simura, Rayko Yamane, Hisanori Lu-atom-ordered oxonitridoaluminosilicate Ba(0.9)Ce(0.1)LuAl(0.2)Si(3.8)N(6.9)O(0.1) |
title | Lu-atom-ordered oxonitridoaluminosilicate Ba(0.9)Ce(0.1)LuAl(0.2)Si(3.8)N(6.9)O(0.1)
|
title_full | Lu-atom-ordered oxonitridoaluminosilicate Ba(0.9)Ce(0.1)LuAl(0.2)Si(3.8)N(6.9)O(0.1)
|
title_fullStr | Lu-atom-ordered oxonitridoaluminosilicate Ba(0.9)Ce(0.1)LuAl(0.2)Si(3.8)N(6.9)O(0.1)
|
title_full_unstemmed | Lu-atom-ordered oxonitridoaluminosilicate Ba(0.9)Ce(0.1)LuAl(0.2)Si(3.8)N(6.9)O(0.1)
|
title_short | Lu-atom-ordered oxonitridoaluminosilicate Ba(0.9)Ce(0.1)LuAl(0.2)Si(3.8)N(6.9)O(0.1)
|
title_sort | lu-atom-ordered oxonitridoaluminosilicate ba(0.9)ce(0.1)lual(0.2)si(3.8)n(6.9)o(0.1) |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7643228/ https://www.ncbi.nlm.nih.gov/pubmed/33209337 http://dx.doi.org/10.1107/S2056989020013158 |
work_keys_str_mv | AT simurarayko luatomorderedoxonitridoaluminosilicateba09ce01lual02si38n69o01 AT yamanehisanori luatomorderedoxonitridoaluminosilicateba09ce01lual02si38n69o01 |