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Structure of tetrakis(μ-decanoato-κ(2) O:O′)bis[(4-methylpyridine-κN)copper(II)], a dimeric copper(II) complex
The 4-methylpyridine (4-Mepy) based dimeric copper(II) carboxylate complex [Cu(2)(C(10)H(19)O(2))(4)(C(6)H(7)N)(2)] or [Cu(2)(μ-O(2)CC(9)H(19))(4)(4-Mepy)(2)] crystallizes with triclinic (P [Image: see text]) symmetry. The two Cu(II) ions exhibit a distorted square-pyramidal environment and are co...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7643230/ https://www.ncbi.nlm.nih.gov/pubmed/33209352 http://dx.doi.org/10.1107/S2056989020014103 |
Sumario: | The 4-methylpyridine (4-Mepy) based dimeric copper(II) carboxylate complex [Cu(2)(C(10)H(19)O(2))(4)(C(6)H(7)N)(2)] or [Cu(2)(μ-O(2)CC(9)H(19))(4)(4-Mepy)(2)] crystallizes with triclinic (P [Image: see text]) symmetry. The two Cu(II) ions exhibit a distorted square-pyramidal environment and are connected into a centrosymmetric paddle-wheel dinuclear cluster [Cu⋯Cu = 2.6472 (8) Å] via four bridging carboxylate ligands arranged in the syn–syn coordination mode. The apical positions around the paddle-wheel copper centers are occupied by the N atoms of the 4-methylpyridine ligands. The structure exhibits disorder of the terminal alkyl carbon atoms in the decanoate chains. |
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