Structure of tetra­kis­(μ-deca­noato-κ(2) O:O′)bis­[(4-methyl­pyridine-κN)copper(II)], a dimeric copper(II) complex

The 4-methyl­pyridine (4-Mepy) based dimeric copper(II) carboxyl­ate complex [Cu(2)(C(10)H(19)O(2))(4)(C(6)H(7)N)(2)] or [Cu(2)(μ-O(2)CC(9)H(19))(4)(4-Mepy)(2)] crystallizes with triclinic (P [Image: see text]) symmetry. The two Cu(II) ions exhibit a distorted square-pyramidal environment and are co...

Descripción completa

Detalles Bibliográficos
Autores principales: Gogoi, Monsumi, Das, Birinchi Kumar
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7643230/
https://www.ncbi.nlm.nih.gov/pubmed/33209352
http://dx.doi.org/10.1107/S2056989020014103
_version_ 1783606239025954816
author Gogoi, Monsumi
Das, Birinchi Kumar
author_facet Gogoi, Monsumi
Das, Birinchi Kumar
author_sort Gogoi, Monsumi
collection PubMed
description The 4-methyl­pyridine (4-Mepy) based dimeric copper(II) carboxyl­ate complex [Cu(2)(C(10)H(19)O(2))(4)(C(6)H(7)N)(2)] or [Cu(2)(μ-O(2)CC(9)H(19))(4)(4-Mepy)(2)] crystallizes with triclinic (P [Image: see text]) symmetry. The two Cu(II) ions exhibit a distorted square-pyramidal environment and are connected into a centrosymmetric paddle-wheel dinuclear cluster [Cu⋯Cu = 2.6472 (8) Å] via four bridging carboxyl­ate ligands arranged in the syn–syn coordination mode. The apical positions around the paddle-wheel copper centers are occupied by the N atoms of the 4-methyl­pyridine ligands. The structure exhibits disorder of the terminal alkyl carbon atoms in the deca­noate chains.
format Online
Article
Text
id pubmed-7643230
institution National Center for Biotechnology Information
language English
publishDate 2020
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-76432302020-11-17 Structure of tetra­kis­(μ-deca­noato-κ(2) O:O′)bis­[(4-methyl­pyridine-κN)copper(II)], a dimeric copper(II) complex Gogoi, Monsumi Das, Birinchi Kumar Acta Crystallogr E Crystallogr Commun Research Communications The 4-methyl­pyridine (4-Mepy) based dimeric copper(II) carboxyl­ate complex [Cu(2)(C(10)H(19)O(2))(4)(C(6)H(7)N)(2)] or [Cu(2)(μ-O(2)CC(9)H(19))(4)(4-Mepy)(2)] crystallizes with triclinic (P [Image: see text]) symmetry. The two Cu(II) ions exhibit a distorted square-pyramidal environment and are connected into a centrosymmetric paddle-wheel dinuclear cluster [Cu⋯Cu = 2.6472 (8) Å] via four bridging carboxyl­ate ligands arranged in the syn–syn coordination mode. The apical positions around the paddle-wheel copper centers are occupied by the N atoms of the 4-methyl­pyridine ligands. The structure exhibits disorder of the terminal alkyl carbon atoms in the deca­noate chains. International Union of Crystallography 2020-10-30 /pmc/articles/PMC7643230/ /pubmed/33209352 http://dx.doi.org/10.1107/S2056989020014103 Text en © Gogoi and Das 2020 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Gogoi, Monsumi
Das, Birinchi Kumar
Structure of tetra­kis­(μ-deca­noato-κ(2) O:O′)bis­[(4-methyl­pyridine-κN)copper(II)], a dimeric copper(II) complex
title Structure of tetra­kis­(μ-deca­noato-κ(2) O:O′)bis­[(4-methyl­pyridine-κN)copper(II)], a dimeric copper(II) complex
title_full Structure of tetra­kis­(μ-deca­noato-κ(2) O:O′)bis­[(4-methyl­pyridine-κN)copper(II)], a dimeric copper(II) complex
title_fullStr Structure of tetra­kis­(μ-deca­noato-κ(2) O:O′)bis­[(4-methyl­pyridine-κN)copper(II)], a dimeric copper(II) complex
title_full_unstemmed Structure of tetra­kis­(μ-deca­noato-κ(2) O:O′)bis­[(4-methyl­pyridine-κN)copper(II)], a dimeric copper(II) complex
title_short Structure of tetra­kis­(μ-deca­noato-κ(2) O:O′)bis­[(4-methyl­pyridine-κN)copper(II)], a dimeric copper(II) complex
title_sort structure of tetra­kis­(μ-deca­noato-κ(2) o:o′)bis­[(4-methyl­pyridine-κn)copper(ii)], a dimeric copper(ii) complex
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7643230/
https://www.ncbi.nlm.nih.gov/pubmed/33209352
http://dx.doi.org/10.1107/S2056989020014103
work_keys_str_mv AT gogoimonsumi structureoftetrakismdecanoatok2oobis4methylpyridinekncopperiiadimericcopperiicomplex
AT dasbirinchikumar structureoftetrakismdecanoatok2oobis4methylpyridinekncopperiiadimericcopperiicomplex

Ejemplares similares