Crystal structure of (N^C) cyclo­metalated Au(III) diazide at 100 K

The title compound, an (N^C)-cyclo­metalated gold(III) diazide, namely, di­azido­[5-eth­oxy­carbonyl-2-(5-eth­oxy­carbonyl­pyridin-2-yl)phenyl-κ(2) C (1),N]gold(III), [Au(C(17)H(16)NO(4))(N(3))(2)] or Au(ppy(Et))(N(3))(2), was synthesized by reacting Au(ppy(Et))Cl(2) with NaN(3) in water for 24 h. T...

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Autores principales: Levchenko, Volodymyr, Øien-Ødegaard, Sigurd, Wragg, David, Tilset, Mats
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7643232/
https://www.ncbi.nlm.nih.gov/pubmed/33209341
http://dx.doi.org/10.1107/S2056989020012955
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author Levchenko, Volodymyr
Øien-Ødegaard, Sigurd
Wragg, David
Tilset, Mats
author_facet Levchenko, Volodymyr
Øien-Ødegaard, Sigurd
Wragg, David
Tilset, Mats
author_sort Levchenko, Volodymyr
collection PubMed
description The title compound, an (N^C)-cyclo­metalated gold(III) diazide, namely, di­azido­[5-eth­oxy­carbonyl-2-(5-eth­oxy­carbonyl­pyridin-2-yl)phenyl-κ(2) C (1),N]gold(III), [Au(C(17)H(16)NO(4))(N(3))(2)] or Au(ppy(Et))(N(3))(2), was synthesized by reacting Au(ppy(Et))Cl(2) with NaN(3) in water for 24 h. The complex has been structurally characterized and features a gold center with a square-planar environment. The Au—N(azide) bond lengths are significantly different depending on the influence of the atom trans to the azide group [Au—N(trans to C) of 2.067 (2) Å versus Au—N(trans to N) of 2.042 (2) Å]. The azide groups are twisted in-and-out of plane by 56.2 (2)°.
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spelling pubmed-76432322020-11-17 Crystal structure of (N^C) cyclo­metalated Au(III) diazide at 100 K Levchenko, Volodymyr Øien-Ødegaard, Sigurd Wragg, David Tilset, Mats Acta Crystallogr E Crystallogr Commun Research Communications The title compound, an (N^C)-cyclo­metalated gold(III) diazide, namely, di­azido­[5-eth­oxy­carbonyl-2-(5-eth­oxy­carbonyl­pyridin-2-yl)phenyl-κ(2) C (1),N]gold(III), [Au(C(17)H(16)NO(4))(N(3))(2)] or Au(ppy(Et))(N(3))(2), was synthesized by reacting Au(ppy(Et))Cl(2) with NaN(3) in water for 24 h. The complex has been structurally characterized and features a gold center with a square-planar environment. The Au—N(azide) bond lengths are significantly different depending on the influence of the atom trans to the azide group [Au—N(trans to C) of 2.067 (2) Å versus Au—N(trans to N) of 2.042 (2) Å]. The azide groups are twisted in-and-out of plane by 56.2 (2)°. International Union of Crystallography 2020-10-09 /pmc/articles/PMC7643232/ /pubmed/33209341 http://dx.doi.org/10.1107/S2056989020012955 Text en © Levchenko et al. 2020 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Levchenko, Volodymyr
Øien-Ødegaard, Sigurd
Wragg, David
Tilset, Mats
Crystal structure of (N^C) cyclo­metalated Au(III) diazide at 100 K
title Crystal structure of (N^C) cyclo­metalated Au(III) diazide at 100 K
title_full Crystal structure of (N^C) cyclo­metalated Au(III) diazide at 100 K
title_fullStr Crystal structure of (N^C) cyclo­metalated Au(III) diazide at 100 K
title_full_unstemmed Crystal structure of (N^C) cyclo­metalated Au(III) diazide at 100 K
title_short Crystal structure of (N^C) cyclo­metalated Au(III) diazide at 100 K
title_sort crystal structure of (n^c) cyclo­metalated au(iii) diazide at 100 k
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7643232/
https://www.ncbi.nlm.nih.gov/pubmed/33209341
http://dx.doi.org/10.1107/S2056989020012955
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AT wraggdavid crystalstructureofnccyclometalatedauiiidiazideat100k
AT tilsetmats crystalstructureofnccyclometalatedauiiidiazideat100k

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