Crystal structure and Hirshfeld surface analysis of di­chlorido­(methanol-κO)bis­(2-methyl­pyridine-κN)copper(II)

In the title complex, [CuCl(2)(C(6)H(7)N)(2)(CH(3)OH)], the copper atom is five-coordinated by two nitro­gen atoms of 2-methyl­pyridine ligands, two chloro ligands and an oxygen atom of the methanol mol­ecule, being in a tetra­gonal–pyramidal environment with N and Cl atoms forming the basal plane....

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Autor principal: Reddy, J. Prakasha
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7643234/
https://www.ncbi.nlm.nih.gov/pubmed/33209351
http://dx.doi.org/10.1107/S2056989020014036
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author Reddy, J. Prakasha
author_facet Reddy, J. Prakasha
author_sort Reddy, J. Prakasha
collection PubMed
description In the title complex, [CuCl(2)(C(6)H(7)N)(2)(CH(3)OH)], the copper atom is five-coordinated by two nitro­gen atoms of 2-methyl­pyridine ligands, two chloro ligands and an oxygen atom of the methanol mol­ecule, being in a tetra­gonal–pyramidal environment with N and Cl atoms forming the basal plane. In the crystal, complex mol­ecules related by the twofold rotation axis are joined into dimeric units by pairs of O—H⋯Cl hydrogen bonds. These dimeric units are assembled through C—H⋯Cl inter­actions into layers parallel to (001).
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spelling pubmed-76432342020-11-17 Crystal structure and Hirshfeld surface analysis of di­chlorido­(methanol-κO)bis­(2-methyl­pyridine-κN)copper(II) Reddy, J. Prakasha Acta Crystallogr E Crystallogr Commun Research Communications In the title complex, [CuCl(2)(C(6)H(7)N)(2)(CH(3)OH)], the copper atom is five-coordinated by two nitro­gen atoms of 2-methyl­pyridine ligands, two chloro ligands and an oxygen atom of the methanol mol­ecule, being in a tetra­gonal–pyramidal environment with N and Cl atoms forming the basal plane. In the crystal, complex mol­ecules related by the twofold rotation axis are joined into dimeric units by pairs of O—H⋯Cl hydrogen bonds. These dimeric units are assembled through C—H⋯Cl inter­actions into layers parallel to (001). International Union of Crystallography 2020-10-23 /pmc/articles/PMC7643234/ /pubmed/33209351 http://dx.doi.org/10.1107/S2056989020014036 Text en © J. Prakasha Reddy 2020 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Reddy, J. Prakasha
Crystal structure and Hirshfeld surface analysis of di­chlorido­(methanol-κO)bis­(2-methyl­pyridine-κN)copper(II)
title Crystal structure and Hirshfeld surface analysis of di­chlorido­(methanol-κO)bis­(2-methyl­pyridine-κN)copper(II)
title_full Crystal structure and Hirshfeld surface analysis of di­chlorido­(methanol-κO)bis­(2-methyl­pyridine-κN)copper(II)
title_fullStr Crystal structure and Hirshfeld surface analysis of di­chlorido­(methanol-κO)bis­(2-methyl­pyridine-κN)copper(II)
title_full_unstemmed Crystal structure and Hirshfeld surface analysis of di­chlorido­(methanol-κO)bis­(2-methyl­pyridine-κN)copper(II)
title_short Crystal structure and Hirshfeld surface analysis of di­chlorido­(methanol-κO)bis­(2-methyl­pyridine-κN)copper(II)
title_sort crystal structure and hirshfeld surface analysis of di­chlorido­(methanol-κo)bis­(2-methyl­pyridine-κn)copper(ii)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7643234/
https://www.ncbi.nlm.nih.gov/pubmed/33209351
http://dx.doi.org/10.1107/S2056989020014036
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