Crystal structure of the unusual coordination polymer catena-poly[[gold(I)-μ-1,2-bis­(di­phenyl­phosphino­thio­yl)ethane-κ(2) S:S′] di­bromido­aurate(I)]

In the title compound, {[Au(C(26)H(24)P(2)S(2))][AuBr(2)]}(n), the gold(I) centres of the cation are coordinated by the P=S groups of the di­sulfide ligands to form a chain polymer parallel to the c axis. Both independent gold atoms lie on the same twofold axis, and the midpoint of the H(2)C—CH(2) b...

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Autores principales: Taouss, Christina, Calvo, Marina, Jones, Peter G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7643243/
https://www.ncbi.nlm.nih.gov/pubmed/33209350
http://dx.doi.org/10.1107/S2056989020013675
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author Taouss, Christina
Calvo, Marina
Jones, Peter G.
author_facet Taouss, Christina
Calvo, Marina
Jones, Peter G.
author_sort Taouss, Christina
collection PubMed
description In the title compound, {[Au(C(26)H(24)P(2)S(2))][AuBr(2)]}(n), the gold(I) centres of the cation are coordinated by the P=S groups of the di­sulfide ligands to form a chain polymer parallel to the c axis. Both independent gold atoms lie on the same twofold axis, and the midpoint of the H(2)C—CH(2) bond lies on an inversion centre. The anions flank the polymeric chain; they are connected to it by short aurophilic inter­actions and C—H⋯Br contacts, and to each other by Br⋯Br contacts.
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spelling pubmed-76432432020-11-17 Crystal structure of the unusual coordination polymer catena-poly[[gold(I)-μ-1,2-bis­(di­phenyl­phosphino­thio­yl)ethane-κ(2) S:S′] di­bromido­aurate(I)] Taouss, Christina Calvo, Marina Jones, Peter G. Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, {[Au(C(26)H(24)P(2)S(2))][AuBr(2)]}(n), the gold(I) centres of the cation are coordinated by the P=S groups of the di­sulfide ligands to form a chain polymer parallel to the c axis. Both independent gold atoms lie on the same twofold axis, and the midpoint of the H(2)C—CH(2) bond lies on an inversion centre. The anions flank the polymeric chain; they are connected to it by short aurophilic inter­actions and C—H⋯Br contacts, and to each other by Br⋯Br contacts. International Union of Crystallography 2020-10-20 /pmc/articles/PMC7643243/ /pubmed/33209350 http://dx.doi.org/10.1107/S2056989020013675 Text en © Taouss et al. 2020 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Taouss, Christina
Calvo, Marina
Jones, Peter G.
Crystal structure of the unusual coordination polymer catena-poly[[gold(I)-μ-1,2-bis­(di­phenyl­phosphino­thio­yl)ethane-κ(2) S:S′] di­bromido­aurate(I)]
title Crystal structure of the unusual coordination polymer catena-poly[[gold(I)-μ-1,2-bis­(di­phenyl­phosphino­thio­yl)ethane-κ(2) S:S′] di­bromido­aurate(I)]
title_full Crystal structure of the unusual coordination polymer catena-poly[[gold(I)-μ-1,2-bis­(di­phenyl­phosphino­thio­yl)ethane-κ(2) S:S′] di­bromido­aurate(I)]
title_fullStr Crystal structure of the unusual coordination polymer catena-poly[[gold(I)-μ-1,2-bis­(di­phenyl­phosphino­thio­yl)ethane-κ(2) S:S′] di­bromido­aurate(I)]
title_full_unstemmed Crystal structure of the unusual coordination polymer catena-poly[[gold(I)-μ-1,2-bis­(di­phenyl­phosphino­thio­yl)ethane-κ(2) S:S′] di­bromido­aurate(I)]
title_short Crystal structure of the unusual coordination polymer catena-poly[[gold(I)-μ-1,2-bis­(di­phenyl­phosphino­thio­yl)ethane-κ(2) S:S′] di­bromido­aurate(I)]
title_sort crystal structure of the unusual coordination polymer catena-poly[[gold(i)-μ-1,2-bis­(di­phenyl­phosphino­thio­yl)ethane-κ(2) s:s′] di­bromido­aurate(i)]
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7643243/
https://www.ncbi.nlm.nih.gov/pubmed/33209350
http://dx.doi.org/10.1107/S2056989020013675
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