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The [3+2] Annulation of CF(3)-Ketimines by Re Catalysis: Access to CF(3)-Containing Amino Heterocycles and Polyamides

Transition metal catalyzed [3 + 2] annulation of imines with double bonds via directed C-H activation offers a direct access to amino cyclic motifs. However, owing to weak coordination and steric hindrance, trifluoromethylated ketimines have been an unaddressed challenge for TM-catalyzed annulations...

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Detalles Bibliográficos
Autores principales: Zhang, Saisai, Liu, Xun-Yong, Chang, Zhenbang, Qiao, Xinxin, Xiong, Heng-Ying, Zhang, Guangwu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7644752/
https://www.ncbi.nlm.nih.gov/pubmed/33196028
http://dx.doi.org/10.1016/j.isci.2020.101705