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The [3+2] Annulation of CF(3)-Ketimines by Re Catalysis: Access to CF(3)-Containing Amino Heterocycles and Polyamides
Transition metal catalyzed [3 + 2] annulation of imines with double bonds via directed C-H activation offers a direct access to amino cyclic motifs. However, owing to weak coordination and steric hindrance, trifluoromethylated ketimines have been an unaddressed challenge for TM-catalyzed annulations...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Elsevier
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7644752/ https://www.ncbi.nlm.nih.gov/pubmed/33196028 http://dx.doi.org/10.1016/j.isci.2020.101705 |