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Deciphering the origin of million-fold reactivity observed for the open core diiron [HO–Fe(III)–O–Fe(IV)[double bond, length as m-dash]O](2+) species towards C–H bond activation: role of spin-states, spin-coupling, and spin-cooperation
High-valent metal–oxo species have been characterised as key intermediates in both heme and non-heme enzymes that are found to perform efficient aliphatic hydroxylation, epoxidation, halogenation, and dehydrogenation reactions. Several biomimetic model complexes have been synthesised over the years...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7654192/ https://www.ncbi.nlm.nih.gov/pubmed/33209248 http://dx.doi.org/10.1039/d0sc02624g |