Green and Fast Synthesis of 2-Arylidene-indan-1,3-diones Using a Task-Specific Ionic Liquid

[Image: see text] A novel method for condensation reaction of indan-1,3-dione with various aldehydes which are efficiently catalyzed by a task-specific ionic liquid, 2-hydroxyethylammonium formate, to provide the corresponding 2-arylidenindane-1,3-diones has been developed. This green, low-cost, hig...

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Autores principales: Alizadeh, Abdolhamid, Beiranvand, Zahra, Safaei, Zahra, Khodaei, Mohammad M., Repo, Eveliina
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7658926/
https://www.ncbi.nlm.nih.gov/pubmed/33195915
http://dx.doi.org/10.1021/acsomega.0c03645
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author Alizadeh, Abdolhamid
Beiranvand, Zahra
Safaei, Zahra
Khodaei, Mohammad M.
Repo, Eveliina
author_facet Alizadeh, Abdolhamid
Beiranvand, Zahra
Safaei, Zahra
Khodaei, Mohammad M.
Repo, Eveliina
author_sort Alizadeh, Abdolhamid
collection PubMed
description [Image: see text] A novel method for condensation reaction of indan-1,3-dione with various aldehydes which are efficiently catalyzed by a task-specific ionic liquid, 2-hydroxyethylammonium formate, to provide the corresponding 2-arylidenindane-1,3-diones has been developed. This green, low-cost, high-yield, and fast reaction takes place at room temperature without the use of any solvent and catalyst. A plausible reaction mechanism that involves ionic liquid-assisted activation is also discussed. This work is the first report of ionic liquids as a reaction medium and catalyst for the synthesis of 2-arylidenindane-1,3-diones.
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spelling pubmed-76589262020-11-13 Green and Fast Synthesis of 2-Arylidene-indan-1,3-diones Using a Task-Specific Ionic Liquid Alizadeh, Abdolhamid Beiranvand, Zahra Safaei, Zahra Khodaei, Mohammad M. Repo, Eveliina ACS Omega [Image: see text] A novel method for condensation reaction of indan-1,3-dione with various aldehydes which are efficiently catalyzed by a task-specific ionic liquid, 2-hydroxyethylammonium formate, to provide the corresponding 2-arylidenindane-1,3-diones has been developed. This green, low-cost, high-yield, and fast reaction takes place at room temperature without the use of any solvent and catalyst. A plausible reaction mechanism that involves ionic liquid-assisted activation is also discussed. This work is the first report of ionic liquids as a reaction medium and catalyst for the synthesis of 2-arylidenindane-1,3-diones. American Chemical Society 2020-10-28 /pmc/articles/PMC7658926/ /pubmed/33195915 http://dx.doi.org/10.1021/acsomega.0c03645 Text en © 2020 The Authors. Published by American Chemical Society This is an open access article published under a Creative Commons Non-Commercial No Derivative Works (CC-BY-NC-ND) Attribution License (http://pubs.acs.org/page/policy/authorchoice_ccbyncnd_termsofuse.html) , which permits copying and redistribution of the article, and creation of adaptations, all for non-commercial purposes.
spellingShingle Alizadeh, Abdolhamid
Beiranvand, Zahra
Safaei, Zahra
Khodaei, Mohammad M.
Repo, Eveliina
Green and Fast Synthesis of 2-Arylidene-indan-1,3-diones Using a Task-Specific Ionic Liquid
title Green and Fast Synthesis of 2-Arylidene-indan-1,3-diones Using a Task-Specific Ionic Liquid
title_full Green and Fast Synthesis of 2-Arylidene-indan-1,3-diones Using a Task-Specific Ionic Liquid
title_fullStr Green and Fast Synthesis of 2-Arylidene-indan-1,3-diones Using a Task-Specific Ionic Liquid
title_full_unstemmed Green and Fast Synthesis of 2-Arylidene-indan-1,3-diones Using a Task-Specific Ionic Liquid
title_short Green and Fast Synthesis of 2-Arylidene-indan-1,3-diones Using a Task-Specific Ionic Liquid
title_sort green and fast synthesis of 2-arylidene-indan-1,3-diones using a task-specific ionic liquid
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7658926/
https://www.ncbi.nlm.nih.gov/pubmed/33195915
http://dx.doi.org/10.1021/acsomega.0c03645
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