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Two-Dimensional Molybdenum Diselenide Tuned by Bimetal Co/Ni Nanoparticles for Oxygen Evolution Reaction

[Image: see text] Herein, we report fabrication of MoSe(2) functionalized with bimetal Co/Ni particles, which shows promising electrochemical performance in oxygen and hydrogen evolution reactions (OER and HER) due to its physicochemical properties such as electronic configuration and great electroc...

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Autores principales: Dymerska, Anna, Kukułka, Wojciech, Wenelska, Karolina, Mijowska, Ewa
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7659139/
https://www.ncbi.nlm.nih.gov/pubmed/33195926
http://dx.doi.org/10.1021/acsomega.0c04024
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author Dymerska, Anna
Kukułka, Wojciech
Wenelska, Karolina
Mijowska, Ewa
author_facet Dymerska, Anna
Kukułka, Wojciech
Wenelska, Karolina
Mijowska, Ewa
author_sort Dymerska, Anna
collection PubMed
description [Image: see text] Herein, we report fabrication of MoSe(2) functionalized with bimetal Co/Ni particles, which shows promising electrochemical performance in oxygen and hydrogen evolution reactions (OER and HER) due to its physicochemical properties such as electronic configuration and great electrochemical stability. We propose functionalization with two transition metals, cobalt and nickel, expecting a synergic effect in electrocatalytic activity in a water splitting reaction. These electrocatalytic reactions are essential for efficient electrochemical energy storage. The thin flakes were obtained by exfoliation of bulk molybdenum diselenide. Next, after deposition of metals, precursors were carbonized. Electrochemical data reveal that the presence of Ni and Co particles boosts electrocatalyst performance, providing a great number of active sites due to their conductivity. Interestingly, the material exhibited great evolution potential and good stability in long-term tests.
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spelling pubmed-76591392020-11-13 Two-Dimensional Molybdenum Diselenide Tuned by Bimetal Co/Ni Nanoparticles for Oxygen Evolution Reaction Dymerska, Anna Kukułka, Wojciech Wenelska, Karolina Mijowska, Ewa ACS Omega [Image: see text] Herein, we report fabrication of MoSe(2) functionalized with bimetal Co/Ni particles, which shows promising electrochemical performance in oxygen and hydrogen evolution reactions (OER and HER) due to its physicochemical properties such as electronic configuration and great electrochemical stability. We propose functionalization with two transition metals, cobalt and nickel, expecting a synergic effect in electrocatalytic activity in a water splitting reaction. These electrocatalytic reactions are essential for efficient electrochemical energy storage. The thin flakes were obtained by exfoliation of bulk molybdenum diselenide. Next, after deposition of metals, precursors were carbonized. Electrochemical data reveal that the presence of Ni and Co particles boosts electrocatalyst performance, providing a great number of active sites due to their conductivity. Interestingly, the material exhibited great evolution potential and good stability in long-term tests. American Chemical Society 2020-10-27 /pmc/articles/PMC7659139/ /pubmed/33195926 http://dx.doi.org/10.1021/acsomega.0c04024 Text en © 2020 American Chemical Society This is an open access article published under a Creative Commons Attribution (CC-BY) License (http://pubs.acs.org/page/policy/authorchoice_ccby_termsofuse.html) , which permits unrestricted use, distribution and reproduction in any medium, provided the author and source are cited.
spellingShingle Dymerska, Anna
Kukułka, Wojciech
Wenelska, Karolina
Mijowska, Ewa
Two-Dimensional Molybdenum Diselenide Tuned by Bimetal Co/Ni Nanoparticles for Oxygen Evolution Reaction
title Two-Dimensional Molybdenum Diselenide Tuned by Bimetal Co/Ni Nanoparticles for Oxygen Evolution Reaction
title_full Two-Dimensional Molybdenum Diselenide Tuned by Bimetal Co/Ni Nanoparticles for Oxygen Evolution Reaction
title_fullStr Two-Dimensional Molybdenum Diselenide Tuned by Bimetal Co/Ni Nanoparticles for Oxygen Evolution Reaction
title_full_unstemmed Two-Dimensional Molybdenum Diselenide Tuned by Bimetal Co/Ni Nanoparticles for Oxygen Evolution Reaction
title_short Two-Dimensional Molybdenum Diselenide Tuned by Bimetal Co/Ni Nanoparticles for Oxygen Evolution Reaction
title_sort two-dimensional molybdenum diselenide tuned by bimetal co/ni nanoparticles for oxygen evolution reaction
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7659139/
https://www.ncbi.nlm.nih.gov/pubmed/33195926
http://dx.doi.org/10.1021/acsomega.0c04024
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