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Effect of Blending Ratio and Temperature on CO(2) Solubility in Blended Aqueous Solution of Monoethanolamine and 2-Amino-2-methyl-propanol: Experimental and Modeling Study Using the Electrolyte Nonrandom Two-Liquid Model

[Image: see text] This paper reports the newly measured experimental data for CO(2) solubility in a blended aqueous solution of monoethanolamine (MEA) and 2-amino-2-methyl-propanol (AMP) at different amine mixing ratios (MEA/AMP/H(2)O = 9:21:70, 15:15:70, and 21:9:70 wt %) and working temperatures (...

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Detalles Bibliográficos
Autores principales: Choi, Bong-Keun, Kim, Seung-Mo, Lee, Jong-Seop, Park, Young Cheol, Chun, Dong-Hyuk, Shin, Hun-Yong, Sung, Hyun-Je, Min, Byoung-Moo, Moon, Jong-Ho
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7659173/
https://www.ncbi.nlm.nih.gov/pubmed/33195927
http://dx.doi.org/10.1021/acsomega.0c04046
Descripción
Sumario:[Image: see text] This paper reports the newly measured experimental data for CO(2) solubility in a blended aqueous solution of monoethanolamine (MEA) and 2-amino-2-methyl-propanol (AMP) at different amine mixing ratios (MEA/AMP/H(2)O = 9:21:70, 15:15:70, and 21:9:70 wt %) and working temperatures (323.15, 373.15, and 383.15 K). The successive substitution method was used for calculating the mole fractions of all molecules (four molecules) and electrolytes (three cations and four anions) from the equilibrium along with the material and charge balance equations (11 equations). The electrolyte nonrandom two-liquid (e-NRTL) model was used to investigate nonideality in the liquid phase. Using the abovementioned thermodynamic models, the partial pressures of CO(2) in the gas phase, mole fractions of all components in the liquid phase, pH variations, heats of absorption, and cyclic capacities of CO(2) according to the absorption/desorption temperature and the blending ratio of MEA/AMP were estimated.