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Effect of Blending Ratio and Temperature on CO(2) Solubility in Blended Aqueous Solution of Monoethanolamine and 2-Amino-2-methyl-propanol: Experimental and Modeling Study Using the Electrolyte Nonrandom Two-Liquid Model

[Image: see text] This paper reports the newly measured experimental data for CO(2) solubility in a blended aqueous solution of monoethanolamine (MEA) and 2-amino-2-methyl-propanol (AMP) at different amine mixing ratios (MEA/AMP/H(2)O = 9:21:70, 15:15:70, and 21:9:70 wt %) and working temperatures (...

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Autores principales: Choi, Bong-Keun, Kim, Seung-Mo, Lee, Jong-Seop, Park, Young Cheol, Chun, Dong-Hyuk, Shin, Hun-Yong, Sung, Hyun-Je, Min, Byoung-Moo, Moon, Jong-Ho
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7659173/
https://www.ncbi.nlm.nih.gov/pubmed/33195927
http://dx.doi.org/10.1021/acsomega.0c04046
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author Choi, Bong-Keun
Kim, Seung-Mo
Lee, Jong-Seop
Park, Young Cheol
Chun, Dong-Hyuk
Shin, Hun-Yong
Sung, Hyun-Je
Min, Byoung-Moo
Moon, Jong-Ho
author_facet Choi, Bong-Keun
Kim, Seung-Mo
Lee, Jong-Seop
Park, Young Cheol
Chun, Dong-Hyuk
Shin, Hun-Yong
Sung, Hyun-Je
Min, Byoung-Moo
Moon, Jong-Ho
author_sort Choi, Bong-Keun
collection PubMed
description [Image: see text] This paper reports the newly measured experimental data for CO(2) solubility in a blended aqueous solution of monoethanolamine (MEA) and 2-amino-2-methyl-propanol (AMP) at different amine mixing ratios (MEA/AMP/H(2)O = 9:21:70, 15:15:70, and 21:9:70 wt %) and working temperatures (323.15, 373.15, and 383.15 K). The successive substitution method was used for calculating the mole fractions of all molecules (four molecules) and electrolytes (three cations and four anions) from the equilibrium along with the material and charge balance equations (11 equations). The electrolyte nonrandom two-liquid (e-NRTL) model was used to investigate nonideality in the liquid phase. Using the abovementioned thermodynamic models, the partial pressures of CO(2) in the gas phase, mole fractions of all components in the liquid phase, pH variations, heats of absorption, and cyclic capacities of CO(2) according to the absorption/desorption temperature and the blending ratio of MEA/AMP were estimated.
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spelling pubmed-76591732020-11-13 Effect of Blending Ratio and Temperature on CO(2) Solubility in Blended Aqueous Solution of Monoethanolamine and 2-Amino-2-methyl-propanol: Experimental and Modeling Study Using the Electrolyte Nonrandom Two-Liquid Model Choi, Bong-Keun Kim, Seung-Mo Lee, Jong-Seop Park, Young Cheol Chun, Dong-Hyuk Shin, Hun-Yong Sung, Hyun-Je Min, Byoung-Moo Moon, Jong-Ho ACS Omega [Image: see text] This paper reports the newly measured experimental data for CO(2) solubility in a blended aqueous solution of monoethanolamine (MEA) and 2-amino-2-methyl-propanol (AMP) at different amine mixing ratios (MEA/AMP/H(2)O = 9:21:70, 15:15:70, and 21:9:70 wt %) and working temperatures (323.15, 373.15, and 383.15 K). The successive substitution method was used for calculating the mole fractions of all molecules (four molecules) and electrolytes (three cations and four anions) from the equilibrium along with the material and charge balance equations (11 equations). The electrolyte nonrandom two-liquid (e-NRTL) model was used to investigate nonideality in the liquid phase. Using the abovementioned thermodynamic models, the partial pressures of CO(2) in the gas phase, mole fractions of all components in the liquid phase, pH variations, heats of absorption, and cyclic capacities of CO(2) according to the absorption/desorption temperature and the blending ratio of MEA/AMP were estimated. American Chemical Society 2020-10-27 /pmc/articles/PMC7659173/ /pubmed/33195927 http://dx.doi.org/10.1021/acsomega.0c04046 Text en © 2020 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Choi, Bong-Keun
Kim, Seung-Mo
Lee, Jong-Seop
Park, Young Cheol
Chun, Dong-Hyuk
Shin, Hun-Yong
Sung, Hyun-Je
Min, Byoung-Moo
Moon, Jong-Ho
Effect of Blending Ratio and Temperature on CO(2) Solubility in Blended Aqueous Solution of Monoethanolamine and 2-Amino-2-methyl-propanol: Experimental and Modeling Study Using the Electrolyte Nonrandom Two-Liquid Model
title Effect of Blending Ratio and Temperature on CO(2) Solubility in Blended Aqueous Solution of Monoethanolamine and 2-Amino-2-methyl-propanol: Experimental and Modeling Study Using the Electrolyte Nonrandom Two-Liquid Model
title_full Effect of Blending Ratio and Temperature on CO(2) Solubility in Blended Aqueous Solution of Monoethanolamine and 2-Amino-2-methyl-propanol: Experimental and Modeling Study Using the Electrolyte Nonrandom Two-Liquid Model
title_fullStr Effect of Blending Ratio and Temperature on CO(2) Solubility in Blended Aqueous Solution of Monoethanolamine and 2-Amino-2-methyl-propanol: Experimental and Modeling Study Using the Electrolyte Nonrandom Two-Liquid Model
title_full_unstemmed Effect of Blending Ratio and Temperature on CO(2) Solubility in Blended Aqueous Solution of Monoethanolamine and 2-Amino-2-methyl-propanol: Experimental and Modeling Study Using the Electrolyte Nonrandom Two-Liquid Model
title_short Effect of Blending Ratio and Temperature on CO(2) Solubility in Blended Aqueous Solution of Monoethanolamine and 2-Amino-2-methyl-propanol: Experimental and Modeling Study Using the Electrolyte Nonrandom Two-Liquid Model
title_sort effect of blending ratio and temperature on co(2) solubility in blended aqueous solution of monoethanolamine and 2-amino-2-methyl-propanol: experimental and modeling study using the electrolyte nonrandom two-liquid model
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7659173/
https://www.ncbi.nlm.nih.gov/pubmed/33195927
http://dx.doi.org/10.1021/acsomega.0c04046
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