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Effect of Blending Ratio and Temperature on CO(2) Solubility in Blended Aqueous Solution of Monoethanolamine and 2-Amino-2-methyl-propanol: Experimental and Modeling Study Using the Electrolyte Nonrandom Two-Liquid Model
[Image: see text] This paper reports the newly measured experimental data for CO(2) solubility in a blended aqueous solution of monoethanolamine (MEA) and 2-amino-2-methyl-propanol (AMP) at different amine mixing ratios (MEA/AMP/H(2)O = 9:21:70, 15:15:70, and 21:9:70 wt %) and working temperatures (...
Autores principales: | , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2020
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7659173/ https://www.ncbi.nlm.nih.gov/pubmed/33195927 http://dx.doi.org/10.1021/acsomega.0c04046 |
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author | Choi, Bong-Keun Kim, Seung-Mo Lee, Jong-Seop Park, Young Cheol Chun, Dong-Hyuk Shin, Hun-Yong Sung, Hyun-Je Min, Byoung-Moo Moon, Jong-Ho |
author_facet | Choi, Bong-Keun Kim, Seung-Mo Lee, Jong-Seop Park, Young Cheol Chun, Dong-Hyuk Shin, Hun-Yong Sung, Hyun-Je Min, Byoung-Moo Moon, Jong-Ho |
author_sort | Choi, Bong-Keun |
collection | PubMed |
description | [Image: see text] This paper reports the newly measured experimental data for CO(2) solubility in a blended aqueous solution of monoethanolamine (MEA) and 2-amino-2-methyl-propanol (AMP) at different amine mixing ratios (MEA/AMP/H(2)O = 9:21:70, 15:15:70, and 21:9:70 wt %) and working temperatures (323.15, 373.15, and 383.15 K). The successive substitution method was used for calculating the mole fractions of all molecules (four molecules) and electrolytes (three cations and four anions) from the equilibrium along with the material and charge balance equations (11 equations). The electrolyte nonrandom two-liquid (e-NRTL) model was used to investigate nonideality in the liquid phase. Using the abovementioned thermodynamic models, the partial pressures of CO(2) in the gas phase, mole fractions of all components in the liquid phase, pH variations, heats of absorption, and cyclic capacities of CO(2) according to the absorption/desorption temperature and the blending ratio of MEA/AMP were estimated. |
format | Online Article Text |
id | pubmed-7659173 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | American Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-76591732020-11-13 Effect of Blending Ratio and Temperature on CO(2) Solubility in Blended Aqueous Solution of Monoethanolamine and 2-Amino-2-methyl-propanol: Experimental and Modeling Study Using the Electrolyte Nonrandom Two-Liquid Model Choi, Bong-Keun Kim, Seung-Mo Lee, Jong-Seop Park, Young Cheol Chun, Dong-Hyuk Shin, Hun-Yong Sung, Hyun-Je Min, Byoung-Moo Moon, Jong-Ho ACS Omega [Image: see text] This paper reports the newly measured experimental data for CO(2) solubility in a blended aqueous solution of monoethanolamine (MEA) and 2-amino-2-methyl-propanol (AMP) at different amine mixing ratios (MEA/AMP/H(2)O = 9:21:70, 15:15:70, and 21:9:70 wt %) and working temperatures (323.15, 373.15, and 383.15 K). The successive substitution method was used for calculating the mole fractions of all molecules (four molecules) and electrolytes (three cations and four anions) from the equilibrium along with the material and charge balance equations (11 equations). The electrolyte nonrandom two-liquid (e-NRTL) model was used to investigate nonideality in the liquid phase. Using the abovementioned thermodynamic models, the partial pressures of CO(2) in the gas phase, mole fractions of all components in the liquid phase, pH variations, heats of absorption, and cyclic capacities of CO(2) according to the absorption/desorption temperature and the blending ratio of MEA/AMP were estimated. American Chemical Society 2020-10-27 /pmc/articles/PMC7659173/ /pubmed/33195927 http://dx.doi.org/10.1021/acsomega.0c04046 Text en © 2020 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes. |
spellingShingle | Choi, Bong-Keun Kim, Seung-Mo Lee, Jong-Seop Park, Young Cheol Chun, Dong-Hyuk Shin, Hun-Yong Sung, Hyun-Je Min, Byoung-Moo Moon, Jong-Ho Effect of Blending Ratio and Temperature on CO(2) Solubility in Blended Aqueous Solution of Monoethanolamine and 2-Amino-2-methyl-propanol: Experimental and Modeling Study Using the Electrolyte Nonrandom Two-Liquid Model |
title | Effect of Blending Ratio and Temperature on CO(2) Solubility in Blended Aqueous Solution of Monoethanolamine
and 2-Amino-2-methyl-propanol: Experimental and Modeling Study
Using the Electrolyte Nonrandom Two-Liquid Model |
title_full | Effect of Blending Ratio and Temperature on CO(2) Solubility in Blended Aqueous Solution of Monoethanolamine
and 2-Amino-2-methyl-propanol: Experimental and Modeling Study
Using the Electrolyte Nonrandom Two-Liquid Model |
title_fullStr | Effect of Blending Ratio and Temperature on CO(2) Solubility in Blended Aqueous Solution of Monoethanolamine
and 2-Amino-2-methyl-propanol: Experimental and Modeling Study
Using the Electrolyte Nonrandom Two-Liquid Model |
title_full_unstemmed | Effect of Blending Ratio and Temperature on CO(2) Solubility in Blended Aqueous Solution of Monoethanolamine
and 2-Amino-2-methyl-propanol: Experimental and Modeling Study
Using the Electrolyte Nonrandom Two-Liquid Model |
title_short | Effect of Blending Ratio and Temperature on CO(2) Solubility in Blended Aqueous Solution of Monoethanolamine
and 2-Amino-2-methyl-propanol: Experimental and Modeling Study
Using the Electrolyte Nonrandom Two-Liquid Model |
title_sort | effect of blending ratio and temperature on co(2) solubility in blended aqueous solution of monoethanolamine
and 2-amino-2-methyl-propanol: experimental and modeling study
using the electrolyte nonrandom two-liquid model |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7659173/ https://www.ncbi.nlm.nih.gov/pubmed/33195927 http://dx.doi.org/10.1021/acsomega.0c04046 |
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