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N5 Is the New C4a: Biochemical Functionalization of Reduced Flavins at the N5 Position

For three decades the C4a-position of reduced flavins was the known site for covalency within flavoenzymes. The reactivity of this position of the reduced isoalloxazine ring with the dioxygen ground-state triplet established the C4a as a site capable of one-electron chemistry. Within the last two de...

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Detalles Bibliográficos
Autores principales: Beaupre, Brett A., Moran, Graham R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7662398/
https://www.ncbi.nlm.nih.gov/pubmed/33195440
http://dx.doi.org/10.3389/fmolb.2020.598912