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N5 Is the New C4a: Biochemical Functionalization of Reduced Flavins at the N5 Position
For three decades the C4a-position of reduced flavins was the known site for covalency within flavoenzymes. The reactivity of this position of the reduced isoalloxazine ring with the dioxygen ground-state triplet established the C4a as a site capable of one-electron chemistry. Within the last two de...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Frontiers Media S.A.
2020
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7662398/ https://www.ncbi.nlm.nih.gov/pubmed/33195440 http://dx.doi.org/10.3389/fmolb.2020.598912 |