Chemistry of Tetradentate [C,N : C,N] Iminophosphorane Palladacycles: Preparation, Reactivity and Theoretical Calculations

A theoretical and experimental study of tetradentate [C,N : C,N] iminophosphorane palladacycles was carried out for the purpose of elucidating their behavior as compared to the parent Schiff base analogues to determine the prospect of encountering new A‐frame structures for the iminophosphorane deri...

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Autores principales: Munín‐Cruz, Paula, Reigosa, Francisco, Rúa‐Sueiro, Marcos, Ortigueira, Juan M., Pereira, M. Teresa, Vila, José M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7670630/
https://www.ncbi.nlm.nih.gov/pubmed/33235825
http://dx.doi.org/10.1002/open.202000253
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author Munín‐Cruz, Paula
Reigosa, Francisco
Rúa‐Sueiro, Marcos
Ortigueira, Juan M.
Pereira, M. Teresa
Vila, José M.
author_facet Munín‐Cruz, Paula
Reigosa, Francisco
Rúa‐Sueiro, Marcos
Ortigueira, Juan M.
Pereira, M. Teresa
Vila, José M.
author_sort Munín‐Cruz, Paula
collection PubMed
description A theoretical and experimental study of tetradentate [C,N : C,N] iminophosphorane palladacycles was carried out for the purpose of elucidating their behavior as compared to the parent Schiff base analogues to determine the prospect of encountering new A‐frame structures for the iminophosphorane derivatives. The DFT calculations were in agreement with the experimental results regarding the performance of these ligands. New insights into the chemistry of the related dinuclear species have been obtained.
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spelling pubmed-76706302020-11-23 Chemistry of Tetradentate [C,N : C,N] Iminophosphorane Palladacycles: Preparation, Reactivity and Theoretical Calculations Munín‐Cruz, Paula Reigosa, Francisco Rúa‐Sueiro, Marcos Ortigueira, Juan M. Pereira, M. Teresa Vila, José M. ChemistryOpen Full Papers A theoretical and experimental study of tetradentate [C,N : C,N] iminophosphorane palladacycles was carried out for the purpose of elucidating their behavior as compared to the parent Schiff base analogues to determine the prospect of encountering new A‐frame structures for the iminophosphorane derivatives. The DFT calculations were in agreement with the experimental results regarding the performance of these ligands. New insights into the chemistry of the related dinuclear species have been obtained. John Wiley and Sons Inc. 2020-11-17 /pmc/articles/PMC7670630/ /pubmed/33235825 http://dx.doi.org/10.1002/open.202000253 Text en © 2020 The Authors. Published by Wiley-VCH GmbH This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc-nd/4.0/ License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.
spellingShingle Full Papers
Munín‐Cruz, Paula
Reigosa, Francisco
Rúa‐Sueiro, Marcos
Ortigueira, Juan M.
Pereira, M. Teresa
Vila, José M.
Chemistry of Tetradentate [C,N : C,N] Iminophosphorane Palladacycles: Preparation, Reactivity and Theoretical Calculations
title Chemistry of Tetradentate [C,N : C,N] Iminophosphorane Palladacycles: Preparation, Reactivity and Theoretical Calculations
title_full Chemistry of Tetradentate [C,N : C,N] Iminophosphorane Palladacycles: Preparation, Reactivity and Theoretical Calculations
title_fullStr Chemistry of Tetradentate [C,N : C,N] Iminophosphorane Palladacycles: Preparation, Reactivity and Theoretical Calculations
title_full_unstemmed Chemistry of Tetradentate [C,N : C,N] Iminophosphorane Palladacycles: Preparation, Reactivity and Theoretical Calculations
title_short Chemistry of Tetradentate [C,N : C,N] Iminophosphorane Palladacycles: Preparation, Reactivity and Theoretical Calculations
title_sort chemistry of tetradentate [c,n : c,n] iminophosphorane palladacycles: preparation, reactivity and theoretical calculations
topic Full Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7670630/
https://www.ncbi.nlm.nih.gov/pubmed/33235825
http://dx.doi.org/10.1002/open.202000253
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