Phosphorus-nitrogen compounds- (Part 50): correlations between structural parameters for cylophosphazene derivatives containing ferrocenyl pendant arm(s)

The results of a systematic study of spiro -cyclotri/tetraphosphazenes with ferrocenyl pendant arm on the basis of correlation between structural parameters were presented. The main parameters were obtained from Xray crystallography and (31)P NMR results in order to investigate the relationship betw...

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Autores principales: ASMAFİLİZ, Nuran, ELMAS, Gamze, OKUMUŞ, Aytuğ, BİLGE KOÇAK, Selen, KILIÇ, Zeynel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Scientific and Technological Research Council of Turkey 2020
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7671203/
https://www.ncbi.nlm.nih.gov/pubmed/33488176
http://dx.doi.org/10.3906/kim-1909-83
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author ASMAFİLİZ, Nuran
ELMAS, Gamze
OKUMUŞ, Aytuğ
BİLGE KOÇAK, Selen
KILIÇ, Zeynel
author_facet ASMAFİLİZ, Nuran
ELMAS, Gamze
OKUMUŞ, Aytuğ
BİLGE KOÇAK, Selen
KILIÇ, Zeynel
author_sort ASMAFİLİZ, Nuran
collection PubMed
description The results of a systematic study of spiro -cyclotri/tetraphosphazenes with ferrocenyl pendant arm on the basis of correlation between structural parameters were presented. The main parameters were obtained from Xray crystallography and (31)P NMR results in order to investigate the relationship between the δ P(spiro) shift values and endocyclic and exocyclic NPN bond angles, and electron density transfer parameters. Structural parameters derived from 11 types of the ferrocenyl cyclophosphazene derivatives with 5- to 7-membered spiro -rings introduced to the literature from our research group were studied and compared with each other.
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spelling pubmed-76712032021-01-22 Phosphorus-nitrogen compounds- (Part 50): correlations between structural parameters for cylophosphazene derivatives containing ferrocenyl pendant arm(s) ASMAFİLİZ, Nuran ELMAS, Gamze OKUMUŞ, Aytuğ BİLGE KOÇAK, Selen KILIÇ, Zeynel Turk J Chem Article The results of a systematic study of spiro -cyclotri/tetraphosphazenes with ferrocenyl pendant arm on the basis of correlation between structural parameters were presented. The main parameters were obtained from Xray crystallography and (31)P NMR results in order to investigate the relationship between the δ P(spiro) shift values and endocyclic and exocyclic NPN bond angles, and electron density transfer parameters. Structural parameters derived from 11 types of the ferrocenyl cyclophosphazene derivatives with 5- to 7-membered spiro -rings introduced to the literature from our research group were studied and compared with each other. The Scientific and Technological Research Council of Turkey 2020-06-01 /pmc/articles/PMC7671203/ /pubmed/33488176 http://dx.doi.org/10.3906/kim-1909-83 Text en Copyright © 2020 The Author(s) This article is distributed under the terms of the Creative Commons Attribution License ( http://creativecommons.org/licenses/by/4.0/ ), which permits unrestricted use and redistribution provided that the original author and source are credited.
spellingShingle Article
ASMAFİLİZ, Nuran
ELMAS, Gamze
OKUMUŞ, Aytuğ
BİLGE KOÇAK, Selen
KILIÇ, Zeynel
Phosphorus-nitrogen compounds- (Part 50): correlations between structural parameters for cylophosphazene derivatives containing ferrocenyl pendant arm(s)
title Phosphorus-nitrogen compounds- (Part 50): correlations between structural parameters for cylophosphazene derivatives containing ferrocenyl pendant arm(s)
title_full Phosphorus-nitrogen compounds- (Part 50): correlations between structural parameters for cylophosphazene derivatives containing ferrocenyl pendant arm(s)
title_fullStr Phosphorus-nitrogen compounds- (Part 50): correlations between structural parameters for cylophosphazene derivatives containing ferrocenyl pendant arm(s)
title_full_unstemmed Phosphorus-nitrogen compounds- (Part 50): correlations between structural parameters for cylophosphazene derivatives containing ferrocenyl pendant arm(s)
title_short Phosphorus-nitrogen compounds- (Part 50): correlations between structural parameters for cylophosphazene derivatives containing ferrocenyl pendant arm(s)
title_sort phosphorus-nitrogen compounds- (part 50): correlations between structural parameters for cylophosphazene derivatives containing ferrocenyl pendant arm(s)
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7671203/
https://www.ncbi.nlm.nih.gov/pubmed/33488176
http://dx.doi.org/10.3906/kim-1909-83
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