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Improvement of the adhesion of conductive poly(m-toluidine) onto chemically reduced-wool fabrics
Wool has disulphide bonds containing-hydrophobic external keratin layers, which act as a barrier for the modification through coating with hydrophilic materials. For that reason, in this work, to ensure a dense and homogenous conductive polymer coating onto the wool, the fabrics were subjected to th...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Scientific and Technological Research Council of Turkey
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7671207/ https://www.ncbi.nlm.nih.gov/pubmed/33488193 http://dx.doi.org/10.3906/kim-2002-77 |
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author | KALKAN ERDOĞAN, Meryem KARAKIŞLA, Meral SAÇAK, Mehmet |
author_facet | KALKAN ERDOĞAN, Meryem KARAKIŞLA, Meral SAÇAK, Mehmet |
author_sort | KALKAN ERDOĞAN, Meryem |
collection | PubMed |
description | Wool has disulphide bonds containing-hydrophobic external keratin layers, which act as a barrier for the modification through coating with hydrophilic materials. For that reason, in this work, to ensure a dense and homogenous conductive polymer coating onto the wool, the fabrics were subjected to the reduction process in the aqueous alkaline medium containing agents that can attack these disulphide bonds. Then, one of the polyaniline derivatives, poly(mtoluidine) (PMT), was coated onto wool by in situ polymerization of m-toluidine sulphate using ammonium persulfate (APS) as an oxidant. The effects of conditions, such as the composition of reduction-bath and types of dopants were investigated, on the mass increase (%) and surface resistivity of the composite. The reduction pretreatment of wool with sodium hydrosulphide significantly improved the coating density, conductivity, and colour shade of PMT on the surface, compared to an untreated one. The coating stability of PMT/wool composite was examined by rubbing test and detergent washing, through surface resistivity measurements. The changes in structural and surface properties of wool fabrics were determined with ATR-FTIR, contact angle, and optical microscopic techniques, respectively. The performance of PMT/wool composite was also examined in the electromagnetic shielding effectiveness (EMSE) measurements within 30 MHz-3 GHz. |
format | Online Article Text |
id | pubmed-7671207 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | The Scientific and Technological Research Council of Turkey |
record_format | MEDLINE/PubMed |
spelling | pubmed-76712072021-01-22 Improvement of the adhesion of conductive poly(m-toluidine) onto chemically reduced-wool fabrics KALKAN ERDOĞAN, Meryem KARAKIŞLA, Meral SAÇAK, Mehmet Turk J Chem Article Wool has disulphide bonds containing-hydrophobic external keratin layers, which act as a barrier for the modification through coating with hydrophilic materials. For that reason, in this work, to ensure a dense and homogenous conductive polymer coating onto the wool, the fabrics were subjected to the reduction process in the aqueous alkaline medium containing agents that can attack these disulphide bonds. Then, one of the polyaniline derivatives, poly(mtoluidine) (PMT), was coated onto wool by in situ polymerization of m-toluidine sulphate using ammonium persulfate (APS) as an oxidant. The effects of conditions, such as the composition of reduction-bath and types of dopants were investigated, on the mass increase (%) and surface resistivity of the composite. The reduction pretreatment of wool with sodium hydrosulphide significantly improved the coating density, conductivity, and colour shade of PMT on the surface, compared to an untreated one. The coating stability of PMT/wool composite was examined by rubbing test and detergent washing, through surface resistivity measurements. The changes in structural and surface properties of wool fabrics were determined with ATR-FTIR, contact angle, and optical microscopic techniques, respectively. The performance of PMT/wool composite was also examined in the electromagnetic shielding effectiveness (EMSE) measurements within 30 MHz-3 GHz. The Scientific and Technological Research Council of Turkey 2020-06-01 /pmc/articles/PMC7671207/ /pubmed/33488193 http://dx.doi.org/10.3906/kim-2002-77 Text en Copyright © 2020 The Author(s) This article is distributed under the terms of the Creative Commons Attribution License ( http://creativecommons.org/licenses/by/4.0/ ), which permits unrestricted use and redistribution provided that the original author and source are credited. |
spellingShingle | Article KALKAN ERDOĞAN, Meryem KARAKIŞLA, Meral SAÇAK, Mehmet Improvement of the adhesion of conductive poly(m-toluidine) onto chemically reduced-wool fabrics |
title | Improvement of the adhesion of conductive poly(m-toluidine) onto chemically reduced-wool fabrics |
title_full | Improvement of the adhesion of conductive poly(m-toluidine) onto chemically reduced-wool fabrics |
title_fullStr | Improvement of the adhesion of conductive poly(m-toluidine) onto chemically reduced-wool fabrics |
title_full_unstemmed | Improvement of the adhesion of conductive poly(m-toluidine) onto chemically reduced-wool fabrics |
title_short | Improvement of the adhesion of conductive poly(m-toluidine) onto chemically reduced-wool fabrics |
title_sort | improvement of the adhesion of conductive poly(m-toluidine) onto chemically reduced-wool fabrics |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7671207/ https://www.ncbi.nlm.nih.gov/pubmed/33488193 http://dx.doi.org/10.3906/kim-2002-77 |
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