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The Model of the Extraction Process of Rare Metals Under Condition of Filtration Combustion Wave

To study the mass transfer of metal compounds, a model of filtration combustion of metal-containing combustible mixtures is developed. Using cadmium-containing mixture as an example, the main characteristics of filtration combustion are determined when the gas pressure at the reactor inlet is consta...

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Autores principales: Salgansky, Eugene A., Lutsenko, Nickolay A., Toledo, Mario
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7674645/
https://www.ncbi.nlm.nih.gov/pubmed/33251180
http://dx.doi.org/10.3389/fchem.2020.511502
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author Salgansky, Eugene A.
Lutsenko, Nickolay A.
Toledo, Mario
author_facet Salgansky, Eugene A.
Lutsenko, Nickolay A.
Toledo, Mario
author_sort Salgansky, Eugene A.
collection PubMed
description To study the mass transfer of metal compounds, a model of filtration combustion of metal-containing combustible mixtures is developed. Using cadmium-containing mixture as an example, the main characteristics of filtration combustion are determined when the gas pressure at the reactor inlet is constant. It is shown that under the conditions of a filtration combustion wave, a metal can evaporate into the gas phase and be transferred with gas through the reactor. Due to the evaporation and condensation of cadmium, it is transported and accumulated before the combustion front. The possibility of controlling the mass transfer of metal compounds under the conditions of a filtration combustion wave with the aim of concentrating them is shown. It is revealed that a 4-fold increase in the pressure difference at the open boundaries of the reactor can lead to a decrease in the maximum metal concentration by about 1.5 times. An increase in the concentration of metals due to mass transfer will subsequently make it economically feasible to extract them by traditional methods.
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spelling pubmed-76746452020-11-27 The Model of the Extraction Process of Rare Metals Under Condition of Filtration Combustion Wave Salgansky, Eugene A. Lutsenko, Nickolay A. Toledo, Mario Front Chem Chemistry To study the mass transfer of metal compounds, a model of filtration combustion of metal-containing combustible mixtures is developed. Using cadmium-containing mixture as an example, the main characteristics of filtration combustion are determined when the gas pressure at the reactor inlet is constant. It is shown that under the conditions of a filtration combustion wave, a metal can evaporate into the gas phase and be transferred with gas through the reactor. Due to the evaporation and condensation of cadmium, it is transported and accumulated before the combustion front. The possibility of controlling the mass transfer of metal compounds under the conditions of a filtration combustion wave with the aim of concentrating them is shown. It is revealed that a 4-fold increase in the pressure difference at the open boundaries of the reactor can lead to a decrease in the maximum metal concentration by about 1.5 times. An increase in the concentration of metals due to mass transfer will subsequently make it economically feasible to extract them by traditional methods. Frontiers Media S.A. 2020-11-05 /pmc/articles/PMC7674645/ /pubmed/33251180 http://dx.doi.org/10.3389/fchem.2020.511502 Text en Copyright © 2020 Salgansky, Lutsenko and Toledo. http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.
spellingShingle Chemistry
Salgansky, Eugene A.
Lutsenko, Nickolay A.
Toledo, Mario
The Model of the Extraction Process of Rare Metals Under Condition of Filtration Combustion Wave
title The Model of the Extraction Process of Rare Metals Under Condition of Filtration Combustion Wave
title_full The Model of the Extraction Process of Rare Metals Under Condition of Filtration Combustion Wave
title_fullStr The Model of the Extraction Process of Rare Metals Under Condition of Filtration Combustion Wave
title_full_unstemmed The Model of the Extraction Process of Rare Metals Under Condition of Filtration Combustion Wave
title_short The Model of the Extraction Process of Rare Metals Under Condition of Filtration Combustion Wave
title_sort model of the extraction process of rare metals under condition of filtration combustion wave
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7674645/
https://www.ncbi.nlm.nih.gov/pubmed/33251180
http://dx.doi.org/10.3389/fchem.2020.511502
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