Cargando…

Isotopic Dependence of Vapor Pressure in Xenon

[Image: see text] The vapor pressure isotopic effect (VPIE) of xenon has been measured using cryogenic distillation. The still is calibrated with argon and krypton and yields a measurement of ln(p(130)/p(136)) ≃ (0.26 ± 0.04) × 10(–3), where p(130) and p(136) are the vapor pressures of (130)Xe and (...

Descripción completa

Detalles Bibliográficos
Autores principales: Alamre, Amal, Badhrees, Ibtesam, Death, Brandon, Licciardi, Caio, Sinclair, David
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7675565/
https://www.ncbi.nlm.nih.gov/pubmed/33225128
http://dx.doi.org/10.1021/acsomega.0c02883
_version_ 1783611675564310528
author Alamre, Amal
Badhrees, Ibtesam
Death, Brandon
Licciardi, Caio
Sinclair, David
author_facet Alamre, Amal
Badhrees, Ibtesam
Death, Brandon
Licciardi, Caio
Sinclair, David
author_sort Alamre, Amal
collection PubMed
description [Image: see text] The vapor pressure isotopic effect (VPIE) of xenon has been measured using cryogenic distillation. The still is calibrated with argon and krypton and yields a measurement of ln(p(130)/p(136)) ≃ (0.26 ± 0.04) × 10(–3), where p(130) and p(136) are the vapor pressures of (130)Xe and (136)Xe at the nominal boiling point, respectively. The dependence of the VPIE across the isotopes for the three elements is found to be approximately linear with atomic mass, and all values are consistent with theoretical expectations.
format Online
Article
Text
id pubmed-7675565
institution National Center for Biotechnology Information
language English
publishDate 2020
publisher American Chemical Society
record_format MEDLINE/PubMed
spelling pubmed-76755652020-11-20 Isotopic Dependence of Vapor Pressure in Xenon Alamre, Amal Badhrees, Ibtesam Death, Brandon Licciardi, Caio Sinclair, David ACS Omega [Image: see text] The vapor pressure isotopic effect (VPIE) of xenon has been measured using cryogenic distillation. The still is calibrated with argon and krypton and yields a measurement of ln(p(130)/p(136)) ≃ (0.26 ± 0.04) × 10(–3), where p(130) and p(136) are the vapor pressures of (130)Xe and (136)Xe at the nominal boiling point, respectively. The dependence of the VPIE across the isotopes for the three elements is found to be approximately linear with atomic mass, and all values are consistent with theoretical expectations. American Chemical Society 2020-11-02 /pmc/articles/PMC7675565/ /pubmed/33225128 http://dx.doi.org/10.1021/acsomega.0c02883 Text en © 2020 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Alamre, Amal
Badhrees, Ibtesam
Death, Brandon
Licciardi, Caio
Sinclair, David
Isotopic Dependence of Vapor Pressure in Xenon
title Isotopic Dependence of Vapor Pressure in Xenon
title_full Isotopic Dependence of Vapor Pressure in Xenon
title_fullStr Isotopic Dependence of Vapor Pressure in Xenon
title_full_unstemmed Isotopic Dependence of Vapor Pressure in Xenon
title_short Isotopic Dependence of Vapor Pressure in Xenon
title_sort isotopic dependence of vapor pressure in xenon
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7675565/
https://www.ncbi.nlm.nih.gov/pubmed/33225128
http://dx.doi.org/10.1021/acsomega.0c02883
work_keys_str_mv AT alamreamal isotopicdependenceofvaporpressureinxenon
AT badhreesibtesam isotopicdependenceofvaporpressureinxenon
AT deathbrandon isotopicdependenceofvaporpressureinxenon
AT licciardicaio isotopicdependenceofvaporpressureinxenon
AT sinclairdavid isotopicdependenceofvaporpressureinxenon