On the mass spectrometric fragmentations of the bacterial sesterterpenes sestermobaraenes A–C

A (13)C-labelling was introduced into each individual carbon of the recently discovered sestermobaraenes by the enzymatic conversion of the correspondingly (13)C-labelled isoprenyl diphosphate precursors with the sestermobaraene synthase from Streptomyces mobaraensis. The main compounds sestermobara...

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Detalles Bibliográficos
Autores principales: Hou, Anwei, Dickschat, Jeroen S
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2020
Materias:
Letter
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7684692/
https://www.ncbi.nlm.nih.gov/pubmed/33281984
http://dx.doi.org/10.3762/bjoc.16.231
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author Hou, Anwei
Dickschat, Jeroen S
author_facet Hou, Anwei
Dickschat, Jeroen S
author_sort Hou, Anwei
collection PubMed
description A (13)C-labelling was introduced into each individual carbon of the recently discovered sestermobaraenes by the enzymatic conversion of the correspondingly (13)C-labelled isoprenyl diphosphate precursors with the sestermobaraene synthase from Streptomyces mobaraensis. The main compounds sestermobaraenes A, B, and C were analysed by gas chromatography–mass spectrometry (GC–MS), allowing for a deep mechanistic investigation of the electron impact mass spectrometry (EIMS) fragmentation reactions of these sesterterpene hydrocarbons.
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spelling pubmed-76846922020-12-04 On the mass spectrometric fragmentations of the bacterial sesterterpenes sestermobaraenes A–C Hou, Anwei Dickschat, Jeroen S Beilstein J Org Chem Letter A (13)C-labelling was introduced into each individual carbon of the recently discovered sestermobaraenes by the enzymatic conversion of the correspondingly (13)C-labelled isoprenyl diphosphate precursors with the sestermobaraene synthase from Streptomyces mobaraensis. The main compounds sestermobaraenes A, B, and C were analysed by gas chromatography–mass spectrometry (GC–MS), allowing for a deep mechanistic investigation of the electron impact mass spectrometry (EIMS) fragmentation reactions of these sesterterpene hydrocarbons. Beilstein-Institut 2020-11-19 /pmc/articles/PMC7684692/ /pubmed/33281984 http://dx.doi.org/10.3762/bjoc.16.231 Text en Copyright © 2020, Hou and Dickschat https://creativecommons.org/licenses/by/4.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0). Please note that the reuse, redistribution and reproduction in particular requires that the authors and source are credited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Letter
Hou, Anwei
Dickschat, Jeroen S
On the mass spectrometric fragmentations of the bacterial sesterterpenes sestermobaraenes A–C
title On the mass spectrometric fragmentations of the bacterial sesterterpenes sestermobaraenes A–C
title_full On the mass spectrometric fragmentations of the bacterial sesterterpenes sestermobaraenes A–C
title_fullStr On the mass spectrometric fragmentations of the bacterial sesterterpenes sestermobaraenes A–C
title_full_unstemmed On the mass spectrometric fragmentations of the bacterial sesterterpenes sestermobaraenes A–C
title_short On the mass spectrometric fragmentations of the bacterial sesterterpenes sestermobaraenes A–C
title_sort on the mass spectrometric fragmentations of the bacterial sesterterpenes sestermobaraenes a–c
topic Letter
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7684692/
https://www.ncbi.nlm.nih.gov/pubmed/33281984
http://dx.doi.org/10.3762/bjoc.16.231
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