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Potential Precursors for Terminal Methylidene Rare‐Earth‐Metal Complexes Supported by a Superbulky Tris(pyrazolyl)borato Ligand

A series of solvent‐free heteroleptic terminal rare‐earth‐metal alkyl complexes stabilized by a superbulky tris(pyrazolyl)borato ligand with the general formula [Tp(tBu,Me)LnMeR] have been synthesized and fully characterized. Treatment of the heterobimetallic mixed methyl/tetramethylaluminate compou...

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Detalles Bibliográficos
Autores principales: Birkelbach, Verena M., Thim, Renita, Stuhl, Christoph, Maichle‐Mössmer, Cäcilia, Anwander, Reiner
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7687121/
https://www.ncbi.nlm.nih.gov/pubmed/31490590
http://dx.doi.org/10.1002/chem.201903606