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Electronic Finetuning of a Bio‐inspired Iron(II) tetra‐NHC Complex by trans Axial Isocyanide Substitution
The synthesis of trans axially substituted mono‐ (1 a) and bis(tert‐butylisocyanide) (1 b) derivatives of the highly active homogeneous bio‐inspired iron(II) olefin epoxidation (pre‐)catalyst 1 bearing an equatorial macrocyclic tetra N‐heterocyclic carbene and two trans axial labile acetonitrile lig...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7687264/ https://www.ncbi.nlm.nih.gov/pubmed/32202690 http://dx.doi.org/10.1002/asia.202000214 |