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Dinuclear Gold(I) Complexes Bearing N,N′‐Allyl‐Bridged Bisimidazolylidene Ligands
A novel N,N’‐allyl‐bridged bisimidazolium salt and a novel dinuclear Ag(I) and a Au(I) NHC complex are reported. Both metallacyclic complexes have a twisted structural shape due to the rigid allylic system and form two different isomers relating to the position of the double bonds. The allyl‐group s...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7687270/ https://www.ncbi.nlm.nih.gov/pubmed/32348033 http://dx.doi.org/10.1002/asia.202000453 |
| _version_ | 1783613495652122624 |
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| author | Jakob, Christian H. G. Dominelli, Bruno Rieb, Julia Jandl, Christian Pöthig, Alexander Reich, Robert M. Correia, João D. G. Kühn, Fritz E. |
| author_facet | Jakob, Christian H. G. Dominelli, Bruno Rieb, Julia Jandl, Christian Pöthig, Alexander Reich, Robert M. Correia, João D. G. Kühn, Fritz E. |
| author_sort | Jakob, Christian H. G. |
| collection | PubMed |
| description | A novel N,N’‐allyl‐bridged bisimidazolium salt and a novel dinuclear Ag(I) and a Au(I) NHC complex are reported. Both metallacyclic complexes have a twisted structural shape due to the rigid allylic system and form two different isomers relating to the position of the double bonds. The allyl‐group shows photoisomerisation, but no reactivity towards bases for the additional coordination of Pd(II). |
| format | Online Article Text |
| id | pubmed-7687270 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2020 |
| publisher | John Wiley and Sons Inc. |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-76872702020-12-05 Dinuclear Gold(I) Complexes Bearing N,N′‐Allyl‐Bridged Bisimidazolylidene Ligands Jakob, Christian H. G. Dominelli, Bruno Rieb, Julia Jandl, Christian Pöthig, Alexander Reich, Robert M. Correia, João D. G. Kühn, Fritz E. Chem Asian J Communications A novel N,N’‐allyl‐bridged bisimidazolium salt and a novel dinuclear Ag(I) and a Au(I) NHC complex are reported. Both metallacyclic complexes have a twisted structural shape due to the rigid allylic system and form two different isomers relating to the position of the double bonds. The allyl‐group shows photoisomerisation, but no reactivity towards bases for the additional coordination of Pd(II). John Wiley and Sons Inc. 2020-05-28 2020-06-17 /pmc/articles/PMC7687270/ /pubmed/32348033 http://dx.doi.org/10.1002/asia.202000453 Text en © 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc-nd/4.0/ License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made. |
| spellingShingle | Communications Jakob, Christian H. G. Dominelli, Bruno Rieb, Julia Jandl, Christian Pöthig, Alexander Reich, Robert M. Correia, João D. G. Kühn, Fritz E. Dinuclear Gold(I) Complexes Bearing N,N′‐Allyl‐Bridged Bisimidazolylidene Ligands |
| title | Dinuclear Gold(I) Complexes Bearing N,N′‐Allyl‐Bridged Bisimidazolylidene Ligands |
| title_full | Dinuclear Gold(I) Complexes Bearing N,N′‐Allyl‐Bridged Bisimidazolylidene Ligands |
| title_fullStr | Dinuclear Gold(I) Complexes Bearing N,N′‐Allyl‐Bridged Bisimidazolylidene Ligands |
| title_full_unstemmed | Dinuclear Gold(I) Complexes Bearing N,N′‐Allyl‐Bridged Bisimidazolylidene Ligands |
| title_short | Dinuclear Gold(I) Complexes Bearing N,N′‐Allyl‐Bridged Bisimidazolylidene Ligands |
| title_sort | dinuclear gold(i) complexes bearing n,n′‐allyl‐bridged bisimidazolylidene ligands |
| topic | Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7687270/ https://www.ncbi.nlm.nih.gov/pubmed/32348033 http://dx.doi.org/10.1002/asia.202000453 |
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