Eosin Y-Catalyzed Synthesis of 3-Aminoimidazo[1,2-a]Pyridines via the HAT Process under Visible Light through Formation of the C–N Bond

[Image: see text] A comfortable, environment-friendly, and metal-free approach for synthesizing the biologically important moiety aminoimidazopyridine through the multicomponent reaction of benzylamine, 2-aminopyridine, and t-butyl isocyanide under visible light using eosin Y as a photocatalyst has...

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Autores principales: Singh, Himanshu Kumar, Kamal, Arsala, Kumari, Savita, Kumar, Dhirendra, Maury, Suresh Kumar, Srivastava, Vandana, Singh, Sundaram
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7689671/
https://www.ncbi.nlm.nih.gov/pubmed/33251420
http://dx.doi.org/10.1021/acsomega.0c03941
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author Singh, Himanshu Kumar
Kamal, Arsala
Kumari, Savita
Kumar, Dhirendra
Maury, Suresh Kumar
Srivastava, Vandana
Singh, Sundaram
author_facet Singh, Himanshu Kumar
Kamal, Arsala
Kumari, Savita
Kumar, Dhirendra
Maury, Suresh Kumar
Srivastava, Vandana
Singh, Sundaram
author_sort Singh, Himanshu Kumar
collection PubMed
description [Image: see text] A comfortable, environment-friendly, and metal-free approach for synthesizing the biologically important moiety aminoimidazopyridine through the multicomponent reaction of benzylamine, 2-aminopyridine, and t-butyl isocyanide under visible light using eosin Y as a photocatalyst has been developed. Inexpensive, nontoxic, the effortless accessibility of starting materials, and nonparticipation of particular glassware and a photoreactor system are important qualities of the current approach. Strangely, the mild conditions, environment-friendly, and enumerating tolerance of an extensive range of both electron-donating and electron-withdrawing groups are additional features of the approach.
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spelling pubmed-76896712020-11-27 Eosin Y-Catalyzed Synthesis of 3-Aminoimidazo[1,2-a]Pyridines via the HAT Process under Visible Light through Formation of the C–N Bond Singh, Himanshu Kumar Kamal, Arsala Kumari, Savita Kumar, Dhirendra Maury, Suresh Kumar Srivastava, Vandana Singh, Sundaram ACS Omega [Image: see text] A comfortable, environment-friendly, and metal-free approach for synthesizing the biologically important moiety aminoimidazopyridine through the multicomponent reaction of benzylamine, 2-aminopyridine, and t-butyl isocyanide under visible light using eosin Y as a photocatalyst has been developed. Inexpensive, nontoxic, the effortless accessibility of starting materials, and nonparticipation of particular glassware and a photoreactor system are important qualities of the current approach. Strangely, the mild conditions, environment-friendly, and enumerating tolerance of an extensive range of both electron-donating and electron-withdrawing groups are additional features of the approach. American Chemical Society 2020-11-12 /pmc/articles/PMC7689671/ /pubmed/33251420 http://dx.doi.org/10.1021/acsomega.0c03941 Text en © 2020 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Singh, Himanshu Kumar
Kamal, Arsala
Kumari, Savita
Kumar, Dhirendra
Maury, Suresh Kumar
Srivastava, Vandana
Singh, Sundaram
Eosin Y-Catalyzed Synthesis of 3-Aminoimidazo[1,2-a]Pyridines via the HAT Process under Visible Light through Formation of the C–N Bond
title Eosin Y-Catalyzed Synthesis of 3-Aminoimidazo[1,2-a]Pyridines via the HAT Process under Visible Light through Formation of the C–N Bond
title_full Eosin Y-Catalyzed Synthesis of 3-Aminoimidazo[1,2-a]Pyridines via the HAT Process under Visible Light through Formation of the C–N Bond
title_fullStr Eosin Y-Catalyzed Synthesis of 3-Aminoimidazo[1,2-a]Pyridines via the HAT Process under Visible Light through Formation of the C–N Bond
title_full_unstemmed Eosin Y-Catalyzed Synthesis of 3-Aminoimidazo[1,2-a]Pyridines via the HAT Process under Visible Light through Formation of the C–N Bond
title_short Eosin Y-Catalyzed Synthesis of 3-Aminoimidazo[1,2-a]Pyridines via the HAT Process under Visible Light through Formation of the C–N Bond
title_sort eosin y-catalyzed synthesis of 3-aminoimidazo[1,2-a]pyridines via the hat process under visible light through formation of the c–n bond
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7689671/
https://www.ncbi.nlm.nih.gov/pubmed/33251420
http://dx.doi.org/10.1021/acsomega.0c03941
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