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Pnictogen-bonding catalysis: brevetoxin-type polyether cyclizations

Pnictogen-bond donors are attractive for use in catalysis because of deep σ holes, high multivalency, rich hypervalency, and chiral binding pockets. We here report natural product inspired epoxide-opening polyether cyclizations catalyzed by fluoroarylated Sb(v) > Sb(iii) > Bi > Sn > Ge....

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Detalles Bibliográficos
Autores principales:	Gini, Andrea, Paraja, Miguel, Galmés, Bartomeu, Besnard, Celine, Poblador-Bahamonde, Amalia I., Sakai, Naomi, Frontera, Antonio, Matile, Stefan
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2020
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7690316/ https://www.ncbi.nlm.nih.gov/pubmed/33250977 http://dx.doi.org/10.1039/d0sc02551h

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