Introduction of Stilbene Derivatives and Cinnamate Ester Derivatives at the ω-End Groups of Poly(Methyl Methacrylate) Prepared via RAFT Polymerization

The capping of “living” poly(methyl methacrylate) (PMMA) and “living” polystyrene (PS), both prepared by the RAFT technique, with various olefins was screened using (19)F-NMR spectroscopy. The capping of “living” PMMA with a labeled stilbene was as high as 63% and with certain cinnamate esters was e...

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Autores principales: Dobinson, Martyn, Hodge, Philip, Wear, Trevor
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7690696/
https://www.ncbi.nlm.nih.gov/pubmed/33113893
http://dx.doi.org/10.3390/polym12112449
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author Dobinson, Martyn
Hodge, Philip
Wear, Trevor
author_facet Dobinson, Martyn
Hodge, Philip
Wear, Trevor
author_sort Dobinson, Martyn
collection PubMed
description The capping of “living” poly(methyl methacrylate) (PMMA) and “living” polystyrene (PS), both prepared by the RAFT technique, with various olefins was screened using (19)F-NMR spectroscopy. The capping of “living” PMMA with a labeled stilbene was as high as 63% and with certain cinnamate esters was essentially quantitative, but the capping of “living” polystyrene with all the olefins investigated was generally poor.
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spelling pubmed-76906962020-11-27 Introduction of Stilbene Derivatives and Cinnamate Ester Derivatives at the ω-End Groups of Poly(Methyl Methacrylate) Prepared via RAFT Polymerization Dobinson, Martyn Hodge, Philip Wear, Trevor Polymers (Basel) Article The capping of “living” poly(methyl methacrylate) (PMMA) and “living” polystyrene (PS), both prepared by the RAFT technique, with various olefins was screened using (19)F-NMR spectroscopy. The capping of “living” PMMA with a labeled stilbene was as high as 63% and with certain cinnamate esters was essentially quantitative, but the capping of “living” polystyrene with all the olefins investigated was generally poor. MDPI 2020-10-23 /pmc/articles/PMC7690696/ /pubmed/33113893 http://dx.doi.org/10.3390/polym12112449 Text en © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Dobinson, Martyn
Hodge, Philip
Wear, Trevor
Introduction of Stilbene Derivatives and Cinnamate Ester Derivatives at the ω-End Groups of Poly(Methyl Methacrylate) Prepared via RAFT Polymerization
title Introduction of Stilbene Derivatives and Cinnamate Ester Derivatives at the ω-End Groups of Poly(Methyl Methacrylate) Prepared via RAFT Polymerization
title_full Introduction of Stilbene Derivatives and Cinnamate Ester Derivatives at the ω-End Groups of Poly(Methyl Methacrylate) Prepared via RAFT Polymerization
title_fullStr Introduction of Stilbene Derivatives and Cinnamate Ester Derivatives at the ω-End Groups of Poly(Methyl Methacrylate) Prepared via RAFT Polymerization
title_full_unstemmed Introduction of Stilbene Derivatives and Cinnamate Ester Derivatives at the ω-End Groups of Poly(Methyl Methacrylate) Prepared via RAFT Polymerization
title_short Introduction of Stilbene Derivatives and Cinnamate Ester Derivatives at the ω-End Groups of Poly(Methyl Methacrylate) Prepared via RAFT Polymerization
title_sort introduction of stilbene derivatives and cinnamate ester derivatives at the ω-end groups of poly(methyl methacrylate) prepared via raft polymerization
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7690696/
https://www.ncbi.nlm.nih.gov/pubmed/33113893
http://dx.doi.org/10.3390/polym12112449
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