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Evaluation of Pd→B Interactions in Diphosphinoborane Complexes and Impact on Inner‐Sphere Reductive Elimination

The dative Pd→B interaction in a series of (R)DPB(R’) Pd(0) and Pd(II) complexes ((R)DPB(R’)=(o‐PR(2)C(6)H(4))(2)BR’, diphosphinoborane) was analyzed using XRD, (11)B NMR spectroscopy and NBO/NLMO calculations. The borane acceptor discriminates between the oxidation state Pd(II) and Pd(0), stabilizi...

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Detalles Bibliográficos
Autores principales:	Ritter, Florian, John, Lukas, Schindler, Tobias, Schroers, Julian P., Teeuwen, Simon, Tauchert, Michael E.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2020
Materias:	Full Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7692930/ https://www.ncbi.nlm.nih.gov/pubmed/32428264 http://dx.doi.org/10.1002/chem.202001189

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