Phosphorus‐Containing Dibenzonaphthanthrenes: Electronic Fine Tuning of Polycyclic Aromatic Hydrocarbons through Organophosphorus Chemistry

A concise synthetic route towards a new family of phosphorus‐containing polycyclic aromatic hydrocarbons starting from the versatile acridophosphine has been established. The structural and optoelectronic properties of these compounds were efficiently modulated through derivatization of the phosphor...

Descripción completa

Detalles Bibliográficos
Autores principales: Ascherl, Johannes D. R., Neiß, Christian, Vogel, Alexander, Graf, Jürgen, Rominger, Frank, Oeser, Thomas, Hampel, Frank, Görling, Andreas, Kivala, Milan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7693108/
https://www.ncbi.nlm.nih.gov/pubmed/32558004
http://dx.doi.org/10.1002/chem.202002872
_version_ 1783614668183437312
author Ascherl, Johannes D. R.
Neiß, Christian
Vogel, Alexander
Graf, Jürgen
Rominger, Frank
Oeser, Thomas
Hampel, Frank
Görling, Andreas
Kivala, Milan
author_facet Ascherl, Johannes D. R.
Neiß, Christian
Vogel, Alexander
Graf, Jürgen
Rominger, Frank
Oeser, Thomas
Hampel, Frank
Görling, Andreas
Kivala, Milan
author_sort Ascherl, Johannes D. R.
collection PubMed
description A concise synthetic route towards a new family of phosphorus‐containing polycyclic aromatic hydrocarbons starting from the versatile acridophosphine has been established. The structural and optoelectronic properties of these compounds were efficiently modulated through derivatization of the phosphorus center. X‐ray crystallographic analysis, UV/Vis spectroscopic, and electrochemical studies supported by DFT calculations identified the considerable potential of these scaffolds for the development of organophosphorus functional materials with tailored properties upon further functionalization.
format Online
Article
Text
id pubmed-7693108
institution National Center for Biotechnology Information
language English
publishDate 2020
publisher John Wiley and Sons Inc.
record_format MEDLINE/PubMed
spelling pubmed-76931082020-12-11 Phosphorus‐Containing Dibenzonaphthanthrenes: Electronic Fine Tuning of Polycyclic Aromatic Hydrocarbons through Organophosphorus Chemistry Ascherl, Johannes D. R. Neiß, Christian Vogel, Alexander Graf, Jürgen Rominger, Frank Oeser, Thomas Hampel, Frank Görling, Andreas Kivala, Milan Chemistry Communications A concise synthetic route towards a new family of phosphorus‐containing polycyclic aromatic hydrocarbons starting from the versatile acridophosphine has been established. The structural and optoelectronic properties of these compounds were efficiently modulated through derivatization of the phosphorus center. X‐ray crystallographic analysis, UV/Vis spectroscopic, and electrochemical studies supported by DFT calculations identified the considerable potential of these scaffolds for the development of organophosphorus functional materials with tailored properties upon further functionalization. John Wiley and Sons Inc. 2020-09-17 2020-10-15 /pmc/articles/PMC7693108/ /pubmed/32558004 http://dx.doi.org/10.1002/chem.202002872 Text en © 2020 The Authors. Published by Wiley-VCH GmbH This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc-nd/4.0/ License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.
spellingShingle Communications
Ascherl, Johannes D. R.
Neiß, Christian
Vogel, Alexander
Graf, Jürgen
Rominger, Frank
Oeser, Thomas
Hampel, Frank
Görling, Andreas
Kivala, Milan
Phosphorus‐Containing Dibenzonaphthanthrenes: Electronic Fine Tuning of Polycyclic Aromatic Hydrocarbons through Organophosphorus Chemistry
title Phosphorus‐Containing Dibenzonaphthanthrenes: Electronic Fine Tuning of Polycyclic Aromatic Hydrocarbons through Organophosphorus Chemistry
title_full Phosphorus‐Containing Dibenzonaphthanthrenes: Electronic Fine Tuning of Polycyclic Aromatic Hydrocarbons through Organophosphorus Chemistry
title_fullStr Phosphorus‐Containing Dibenzonaphthanthrenes: Electronic Fine Tuning of Polycyclic Aromatic Hydrocarbons through Organophosphorus Chemistry
title_full_unstemmed Phosphorus‐Containing Dibenzonaphthanthrenes: Electronic Fine Tuning of Polycyclic Aromatic Hydrocarbons through Organophosphorus Chemistry
title_short Phosphorus‐Containing Dibenzonaphthanthrenes: Electronic Fine Tuning of Polycyclic Aromatic Hydrocarbons through Organophosphorus Chemistry
title_sort phosphorus‐containing dibenzonaphthanthrenes: electronic fine tuning of polycyclic aromatic hydrocarbons through organophosphorus chemistry
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7693108/
https://www.ncbi.nlm.nih.gov/pubmed/32558004
http://dx.doi.org/10.1002/chem.202002872
work_keys_str_mv AT ascherljohannesdr phosphoruscontainingdibenzonaphthanthreneselectronicfinetuningofpolycyclicaromatichydrocarbonsthroughorganophosphoruschemistry
AT neißchristian phosphoruscontainingdibenzonaphthanthreneselectronicfinetuningofpolycyclicaromatichydrocarbonsthroughorganophosphoruschemistry
AT vogelalexander phosphoruscontainingdibenzonaphthanthreneselectronicfinetuningofpolycyclicaromatichydrocarbonsthroughorganophosphoruschemistry
AT grafjurgen phosphoruscontainingdibenzonaphthanthreneselectronicfinetuningofpolycyclicaromatichydrocarbonsthroughorganophosphoruschemistry
AT romingerfrank phosphoruscontainingdibenzonaphthanthreneselectronicfinetuningofpolycyclicaromatichydrocarbonsthroughorganophosphoruschemistry
AT oeserthomas phosphoruscontainingdibenzonaphthanthreneselectronicfinetuningofpolycyclicaromatichydrocarbonsthroughorganophosphoruschemistry
AT hampelfrank phosphoruscontainingdibenzonaphthanthreneselectronicfinetuningofpolycyclicaromatichydrocarbonsthroughorganophosphoruschemistry
AT gorlingandreas phosphoruscontainingdibenzonaphthanthreneselectronicfinetuningofpolycyclicaromatichydrocarbonsthroughorganophosphoruschemistry
AT kivalamilan phosphoruscontainingdibenzonaphthanthreneselectronicfinetuningofpolycyclicaromatichydrocarbonsthroughorganophosphoruschemistry

Ejemplares similares