Cargando…

A Visible‐Light‐Powered Polymerization Method for the Immobilization of Enantioselective Organocatalysts into Microreactors

A versatile one‐step photopolymerization approach for the immobilization of enantioselective organocatalysts is presented. Chiral organocatalyst‐containing monoliths based on polystyrene divinylbenzene copolymer were generated inside channels of microfluidic chips. Exemplary performance tests were p...

Descripción completa

Detalles Bibliográficos
Autores principales:	Warias, Rico, Ragno, Daniele, Massi, Alessandro, Belder, Detlev
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2020
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7693110/ https://www.ncbi.nlm.nih.gov/pubmed/32453458 http://dx.doi.org/10.1002/chem.202002063

Ejemplares similares

Combined bead polymerization and Cinchona organocatalyst immobilization by thiol–ene addition
por: Fredriksen, Kim A, et al.
Publicado: (2012)

A complementary pair of enantioselective switchable organocatalysts
por: De Bo, Guillaume, et al.
Publicado: (2017)

Chiral Diol-Based Organocatalysts in Enantioselective Reactions
por: Nguyen, Truong N., et al.
Publicado: (2018)

Efficiency in Carbon Dioxide Fixation into Cyclic Carbonates: Operating Bifunctional Polyhydroxylated Pyridinium Organocatalysts in Segmented Flow Conditions
por: Poletti, Lorenzo, et al.
Publicado: (2023)

Design and Effects of the Cinnamic Acids Chemical Structures as Organocatalyst on the Polymerization of Benzoxazines
por: Rodríguez, Rocío B., et al.
Publicado: (2020)

Enantioselective, Visible Light Mediated Aza Paternò–Büchi Reactions of Quinoxalinones
por: Li, Xinyao, et al.
Publicado: (2020)

Catalytic Enantioselective Pictet–Spengler Reaction of α‐Ketoamides Catalyzed by a Single H‐Bond Donor Organocatalyst
por: Andres, Rémi, et al.
Publicado: (2022)

Enantioselective bromination of axially chiral cyanoarenes in the presence of bifunctional organocatalysts
por: Wada, Yuuki, et al.
Publicado: (2019)

Reaction-based machine learning representations for predicting the enantioselectivity of organocatalysts
por: Gallarati, Simone, et al.
Publicado: (2021)

Chiral bifunctional organocatalysts for enantioselective synthesis of 3-substituted isoindolinones
por: Hu, Xiao-Mu, et al.
Publicado: (2023)

N-Heterocyclic Olefins as Organocatalysts for Polymerization: Preparation of Well-Defined Poly(propylene oxide)**
por: Naumann, Stefan, et al.
Publicado: (2015)

An Integrated Chemiluminescence Microreactor for Ultrastrong and Long‐Lasting Light Emission
por: Xiao, Zhenyu, et al.
Publicado: (2020)

Anionic Polymerization Using Flow Microreactors
por: Takahashi, Yusuke, et al.
Publicado: (2019)

Enantioselective Michael Addition of 3-Aryl-Substituted Oxindoles to Methyl Vinyl Ketone Catalyzed by a Binaphthyl-Modified Bifunctional Organocatalyst
por: Lee, Hyun Joo, et al.
Publicado: (2012)

A novel recyclable organocatalyst for the gram-scale enantioselective synthesis of (S)-baclofen
por: Dargó, Gyula, et al.
Publicado: (2023)

A Bidentate Iodine(III)‐Based Halogen‐Bond Donor as a Powerful Organocatalyst
por: Heinen, Flemming, et al.
Publicado: (2021)

Bifunctional Iminophosphorane Organocatalysts for Enantioselective Synthesis: Application to the Ketimine Nitro-Mannich Reaction
por: Núñez, Marta G., et al.
Publicado: (2013)

An accessible visible-light actinometer for the determination of photon flux and optical pathlength in flow photo microreactors
por: Roibu, Anca, et al.
Publicado: (2018)

Ring-Opening Polymerization of Trimethylene Carbonate with Phosphazene Organocatalyst
por: Zhu, Jianglin, et al.
Publicado: (2023)

Multivalent polyglycerol supported imidazolidin-4-one organocatalysts for enantioselective Friedel–Crafts alkylations
por: Pecchioli, Tommaso, et al.
Publicado: (2015)

A chiral pentanidium and pyridinyl-sulphonamide ion pair as an enantioselective organocatalyst for Steglich rearrangement
por: Yang, Ziqi, et al.
Publicado: (2023)

U.S. Food and Drug Administration-Certified Food Dyes as Organocatalysts in the Visible Light-Promoted Chlorination of Aromatics and Heteroaromatics
por: Rogers, David A., et al.
Publicado: (2020)

Biocatalytic Synthesis Using Self‐Assembled Polymeric Nano‐ and Microreactors
por: Wang, Yangxin, et al.
Publicado: (2022)

Enantioselective addition of diphenyl phosphonate to ketimines derived from isatins catalyzed by binaphthyl-modified organocatalysts
por: Jang, Hee Seung, et al.
Publicado: (2016)

Novel amide-functionalized chloramphenicol base bifunctional organocatalysts for enantioselective alcoholysis of meso-cyclic anhydrides
por: Xu, Lingjun, et al.
Publicado: (2018)

Polymer Nanofibers Exhibiting Remarkable Activity in Driving the Living Polymerization under Visible Light and Reusability
por: Xia, Lei, et al.
Publicado: (2020)

Immobilized enzyme microreactors for analysis of tryptic peptides in β-casein and β-lactoglobulin
por: Rodzik, Agnieszka, et al.
Publicado: (2023)

Synthesis and evaluation of new guanidine-thiourea organocatalyst for the nitro-Michael reaction: Theoretical studies on mechanism and enantioselectivity
por: Shubina, Tatyana E, et al.
Publicado: (2012)

Enantioselective Michael addition of 2-hydroxy-1,4-naphthoquinones to nitroalkenes catalyzed by binaphthyl-derived organocatalysts
por: Woo, Saet Byeol, et al.
Publicado: (2012)

Chiral ion-pair organocatalyst promotes highly enantioselective 3-exo iodo-cycloetherification of allyl alcohols
por: Shen, Zhigao, et al.
Publicado: (2015)

Polymeric Microreactors with pH-Controlled Spatial Localization of Cascade Reactions
por: Ivanov, Tsvetomir, et al.
Publicado: (2023)

Microreactors—A Powerful Tool to Synthesize Peroxycarboxylic Esters
por: Illg, Tobias, et al.
Publicado: (2015)

Visible‐Light‐Driven CO(2) Reduction by Mesoporous Carbon Nitride Modified with Polymeric Cobalt Phthalocyanine
por: Roy, Souvik, et al.
Publicado: (2019)

Immobilizing a visible light-responsive photocatalyst on a recyclable polymeric composite for floating and suspended applications in water treatment
por: Mehmood, Ch. Tahir, et al.
Publicado: (2020)

A Compartmented Flow Microreactor System for Automated Optimization of Bioprocesses Applying Immobilized Enzymes
por: Heinzler, Raphael, et al.
Publicado: (2018)

Studying the Ring-Opening Polymerization of 1,5-Dioxepan-2-one with Organocatalysts
por: Xu, Jinbao, et al.
Publicado: (2019)

Light‐Driven Enantioselective Organocatalytic β‐Benzylation of Enals
por: Dell'Amico, Luca, et al.
Publicado: (2017)

Highly enantioselective sulfa-Michael addition reactions using N-heterocyclic carbene as a non-covalent organocatalyst
por: Chen, Jiean, et al.
Publicado: (2015)

Enantioselective Michael Addition of Cyclic β-Diones to α,β-Unsaturated Enones Catalyzed by Quinine-Based Organocatalysts
por: Wang, Qingqing, et al.
Publicado: (2017)

Synthesis and Applications of Cinchona Squaramide‐Modified Poly(Glycidyl Methacrylate) Microspheres as Recyclable Polymer‐Grafted Enantioselective Organocatalysts
por: Nagy, Sándor, et al.
Publicado: (2020)

Cannot write session to /tmp/vufind_sessions/sess_tbq8dgv0qkbajpjflbobmqgif0