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Janus Face All‐cis 1,2,4,5‐tetrakis(trifluoromethyl)‐ and All‐cis 1,2,3,4,5,6‐hexakis(trifluoromethyl)‐ Cyclohexanes

We report the synthesis of all‐cis 1,2,4,5‐tetrakis (trifluoromethyl)‐ and all‐cis 1,2,3,4,5,6‐hexakis (trifluoromethyl)‐ cyclohexanes by direct hydrogenation of precursor tetrakis‐ or hexakis‐ (trifluoromethyl)benzenes. The resultant cyclohexanes have a stereochemistry such that all the CF(3) group...

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Detalles Bibliográficos
Autores principales: Yu, Cihang, Kütt, Agnes, Röschenthaler, Gerd‐Volker, Lebl, Tomas, Cordes, David B., Slawin, Alexandra M. Z., Bühl, Michael, O'Hagan, David
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7693182/
https://www.ncbi.nlm.nih.gov/pubmed/32691941
http://dx.doi.org/10.1002/anie.202008662

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