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Self‐Assembled Anion‐Binding Cryptand for the Selective Liquid–Liquid Extraction of Phosphate Anions
The ligands L(1) and L(2) form trinuclear self‐assembled complexes with Cu(2+) (i.e. [(L(1))(2)Cu(3)](6+) or [(L(2))(2)Cu(3)](6+)) both of which act as a host to a variety of anions. Inclusion of long aliphatic chains on these ligands allows the assemblies to extract anions from aqueous media into o...
| Autores principales: | , , , , , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7693201/ https://www.ncbi.nlm.nih.gov/pubmed/32743891 http://dx.doi.org/10.1002/anie.202009960 |
| _version_ | 1783614689094139904 |
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| author | Andrews, Rebecca Begum, Sabera Clemett, Christopher J. Faulkner, Robert A. Ginger, Michael L. Harmer, Jane Molinari, Marco Parkes, Gareth M. B. Qureshi, Zuhlqurnain M. H. Rice, Craig R. Ward, Michael D. Williams, Howard M. Wilson, Philippe B. |
| author_facet | Andrews, Rebecca Begum, Sabera Clemett, Christopher J. Faulkner, Robert A. Ginger, Michael L. Harmer, Jane Molinari, Marco Parkes, Gareth M. B. Qureshi, Zuhlqurnain M. H. Rice, Craig R. Ward, Michael D. Williams, Howard M. Wilson, Philippe B. |
| author_sort | Andrews, Rebecca |
| collection | PubMed |
| description | The ligands L(1) and L(2) form trinuclear self‐assembled complexes with Cu(2+) (i.e. [(L(1))(2)Cu(3)](6+) or [(L(2))(2)Cu(3)](6+)) both of which act as a host to a variety of anions. Inclusion of long aliphatic chains on these ligands allows the assemblies to extract anions from aqueous media into organic solvents. Phosphate can be removed from water efficiently and highly selectively, even in the presence of other anions. |
| format | Online Article Text |
| id | pubmed-7693201 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2020 |
| publisher | John Wiley and Sons Inc. |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-76932012020-12-11 Self‐Assembled Anion‐Binding Cryptand for the Selective Liquid–Liquid Extraction of Phosphate Anions Andrews, Rebecca Begum, Sabera Clemett, Christopher J. Faulkner, Robert A. Ginger, Michael L. Harmer, Jane Molinari, Marco Parkes, Gareth M. B. Qureshi, Zuhlqurnain M. H. Rice, Craig R. Ward, Michael D. Williams, Howard M. Wilson, Philippe B. Angew Chem Int Ed Engl Communications The ligands L(1) and L(2) form trinuclear self‐assembled complexes with Cu(2+) (i.e. [(L(1))(2)Cu(3)](6+) or [(L(2))(2)Cu(3)](6+)) both of which act as a host to a variety of anions. Inclusion of long aliphatic chains on these ligands allows the assemblies to extract anions from aqueous media into organic solvents. Phosphate can be removed from water efficiently and highly selectively, even in the presence of other anions. John Wiley and Sons Inc. 2020-09-02 2020-11-09 /pmc/articles/PMC7693201/ /pubmed/32743891 http://dx.doi.org/10.1002/anie.202009960 Text en © 2020 The Authors. Published by Wiley-VCH GmbH This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited. |
| spellingShingle | Communications Andrews, Rebecca Begum, Sabera Clemett, Christopher J. Faulkner, Robert A. Ginger, Michael L. Harmer, Jane Molinari, Marco Parkes, Gareth M. B. Qureshi, Zuhlqurnain M. H. Rice, Craig R. Ward, Michael D. Williams, Howard M. Wilson, Philippe B. Self‐Assembled Anion‐Binding Cryptand for the Selective Liquid–Liquid Extraction of Phosphate Anions |
| title | Self‐Assembled Anion‐Binding Cryptand for the Selective Liquid–Liquid Extraction of Phosphate Anions |
| title_full | Self‐Assembled Anion‐Binding Cryptand for the Selective Liquid–Liquid Extraction of Phosphate Anions |
| title_fullStr | Self‐Assembled Anion‐Binding Cryptand for the Selective Liquid–Liquid Extraction of Phosphate Anions |
| title_full_unstemmed | Self‐Assembled Anion‐Binding Cryptand for the Selective Liquid–Liquid Extraction of Phosphate Anions |
| title_short | Self‐Assembled Anion‐Binding Cryptand for the Selective Liquid–Liquid Extraction of Phosphate Anions |
| title_sort | self‐assembled anion‐binding cryptand for the selective liquid–liquid extraction of phosphate anions |
| topic | Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7693201/ https://www.ncbi.nlm.nih.gov/pubmed/32743891 http://dx.doi.org/10.1002/anie.202009960 |
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