Cargando…
A Mechanistic Study on Reactions of Group 13 Diyls LM with Cp*SbX(2): From Stibanyl Radicals to Antimony Hydrides
Oxidative addition of Cp*SbX(2) (X=Cl, Br, I; Cp*=C(5)Me(5)) to group 13 diyls LM (M=Al, Ga, In; L=HC[C(Me)N (Dip)](2), Dip=2,6‐iPr(2)C(6)H(3)) yields elemental antimony (M=Al) or the corresponding stibanylgallanes [L(X)Ga]Sb(X)Cp* (X=Br 1, I 2) and ‐indanes [L(X)In]Sb(X)Cp* (X=Cl 5, Br 6, I 7). 1 a...
| Autores principales: | , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7693246/ https://www.ncbi.nlm.nih.gov/pubmed/32428370 http://dx.doi.org/10.1002/chem.202001739 |