Cargando…

Synthesis and Characterization of Tetrakis(pentafluoroethyl)aluminate

While perfluorinated aryl, aryloxy and alkoxy aluminum species are well‐established as weakly coordinating anions (WCAs), corresponding perfluoroalkyl aluminum derivatives are virtually unknown. Reaction of Si(C(2)F(5))(3)CH(3) with Li[AlH(4)] afforded the tetrakis(pentafluoroethyl)aluminate, [Al(C(...

Descripción completa

Detalles Bibliográficos
Autores principales:	Tiessen, Natalia, Neumann, Beate, Stammler, Hans‐Georg, Hoge, Berthold
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2020
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7693355/ https://www.ncbi.nlm.nih.gov/pubmed/32196783 http://dx.doi.org/10.1002/chem.202000668

Ejemplares similares

Tris(pentafluoroethyl)silanol Derivatives and the Lewis Amphoteric Tris(pentafluoroethyl)silanolate Anion, [Si(C(2)F(5))(3)O](−)
por: Tiessen, Natalia, et al.
Publicado: (2021)

Tetrakis(pentafluoroethyl)gallate, [Ga(C(2)F(5))(4)](−), Ionic Liquids
por: Biller, Harry, et al.
Publicado: (2021)

Evidence of the Lewis‐Amphoteric Character of Tris(pentafluoroethyl)silanide, [Si(C(2)F(5))(3)](−)
por: Tiessen, Natalia, et al.
Publicado: (2021)

Synthesis and Reactivity of the First Isolated Hydrogen‐Bridged Silanol–Silanolate Anions
por: Weitkamp, Robin F., et al.
Publicado: (2020)

Oxidative Additions of C−F Bonds to the Silanide Anion [Si(C(2)F(5))(3)](−)
por: Tiessen, Natalia, et al.
Publicado: (2022)

The Influence of Weakly Coordinating Cations on the O−H⋅⋅⋅O(−) Hydrogen Bond of Silanol‐Silanolate Anions
por: Weitkamp, Robin F., et al.
Publicado: (2020)

Non‐Coordinated Phenolate Anions and Their Application in SF(6) Activation
por: Weitkamp, Robin F., et al.
Publicado: (2020)

Generation and Applications of the Hydroxide Trihydrate Anion, [OH(OH(2))(3)](−), Stabilized by a Weakly Coordinating Cation
por: Weitkamp, Robin F., et al.
Publicado: (2019)

Phosphorus‐Containing Superbases: Recent Progress in the Chemistry of Electron‐Abundant Phosphines and Phosphazenes
por: Weitkamp, Robin F., et al.
Publicado: (2021)

Non‐coordinated and Hydrogen Bonded Phenolate Anions as One‐Electron Reducing Agents
por: Weitkamp, Robin F., et al.
Publicado: (2021)

Nickel‐Catalyzed Intramolecular 1,2‐Aryl Migration of Mesoionic Carbenes (iMICs)
por: Merschel, Arne, et al.
Publicado: (2020)

Carbon–carbon bond cleavage for Cu-mediated aromatic trifluoromethylations and pentafluoroethylations
por: Sugiishi, Tsuyuka, et al.
Publicado: (2015)

Distannabarrelenes with Three Coordinated Sn(II) Atoms
por: Sharma, Mahendra K., et al.
Publicado: (2020)

Tris(pentafluoroethyl)difluorophosphorane: A Versatile Fluoride Acceptor for Transition Metal Chemistry
por: Föhrenbacher, Steffen A., et al.
Publicado: (2021)

An Adduct of Sulfur Monoxide to a Frustrated Sn/P Lewis Pair
por: Holtkamp, Philipp, et al.
Publicado: (2020)

An Open‐Shell Singlet Sn(I) Diradical and H(2) Splitting
por: Sharma, Mahendra K., et al.
Publicado: (2021)

Isolation of 1,4‐Diarsinine‐1,4‐diide and 1,4‐Diarsinine Derivatives
por: Rottschäfer, Dennis, et al.
Publicado: (2021)

Structurally Stimulated Deprotonation/Alumination of the TMP Anion**
por: Conway, Ben, et al.
Publicado: (2010)

The Nature of Chalcogen‐Bonding‐Type Tellurium–Nitrogen Interactions: A First Experimental Structure from the Gas Phase
por: Glodde, Timo, et al.
Publicado: (2020)

Crystal Structures of the Carborane Dianions [1,4-(PhCB(10)H(10)C)(2)C(6)H(4)](2−) and [1,4-(PhCB(10)H(10)C)(2)C(6)F(4)](2−) and the Stabilizing Role of the para-Phenylene Unit on 2 n+3 Skeletal Electron Clusters**
por: Kahlert, Jan, et al.
Publicado: (2014)

Isolation of an Arsenic Diradicaloid with a Cyclic C(2)As(2)‐Core
por: Steffenfauseweh, Henric, et al.
Publicado: (2022)

Aryl–Aryl Interactions in (Aryl‐Perhalogenated) 1,2‐Diaryldisilanes
por: Linnemannstöns, Marvin, et al.
Publicado: (2020)

Regiochemical Control in Triptycene Formation—An Exercise in Subtle Balancing Multiple Factors
por: Lamm, Jan‐Hendrik, et al.
Publicado: (2018)

Crystalline Divinyldiarsene Radical Cations and Dications
por: Sharma, Mahendra K., et al.
Publicado: (2019)

A Zwitterionic Phosphonium Stannate(II) via Hydrogen Splitting by a Sn/P Frustrated Lewis‐Pair and Reductive Elimination
por: Holtkamp, Philipp, et al.
Publicado: (2020)

Crystal structure of bis(propane-1,3-diaminium) hexafluoridoaluminate diaquatetrafluoridoaluminate tetrahydrate
por: Abdi, Insaf, et al.
Publicado: (2014)

Potassium chloridotris(hypersiloxy)aluminate dimer
por: Purdy, Andrew P., et al.
Publicado: (2019)

Synthesis of Calcium Aluminates from Non-Saline Aluminum Dross
por: López, Félix Antonio, et al.
Publicado: (2019)

Calix[4]pyrrolato Aluminates: The Effect of Ligand Modification on the Reactivity of Square‐Planar Aluminum Anions
por: Ebner, Fabian, et al.
Publicado: (2021)

Calix[4]pyrrolato Aluminate Catalyzes the Dehydrocoupling of Phenylphosphine Borane to High Molar Weight Polymers
por: Schön, Florian, et al.
Publicado: (2022)

Crystal structure of tert-butyl-N-phenylcarbonitrilium tetrachloridoaluminate
por: van Dijk, Tom, et al.
Publicado: (2014)

Chlorido(η(4)-1,5-cyclooctadiene)[(pentafluoroethyl)diphenylphosphane]iridium(I)
por: Choate, Michelle M., et al.
Publicado: (2010)

Ionic Liquids as Working Fluids for Heat Storage Applications: Decomposition Behavior of N-Butyl-N-methylpyrrolidinium tris(pentafluoroethyl)trifluorophosphate
por: Nardelli, Francesca, et al.
Publicado: (2023)

Direct functionalization of white phosphorus with anionic dicarbenes and mesoionic carbenes: facile access to 1,2,3-triphosphol-2-ides
por: Rottschäfer, Dennis, et al.
Publicado: (2019)

Crystal structure of lutetium aluminate (LUAM), Lu(4)Al(2)O(9)
por: Simura, Rayko, et al.
Publicado: (2020)

Kekulé diradicaloids derived from a classical N-heterocyclic carbene
por: Rottschäfer, Dennis, et al.
Publicado: (2018)

Exploring the Reactivity of a Frustrated Sn/P Lewis Pair: The Highly Selective Complexation of the cis‐Azobenzene Photoisomer
por: Holtkamp, Philipp, et al.
Publicado: (2021)

Mesoionic Dithiolates (MIDts) Derived from 1,3‐Imidazole‐Based Anionic Dicarbenes (ADCs)
por: Ebeler, Falk, et al.
Publicado: (2022)

Differences in the Reactivity of Geminal Si−O−P and Al−O−P Frustrated Lewis Pairs
por: Wickemeyer, Lucas, et al.
Publicado: (2022)

Regioisomer-Free C(4h) β-Tetrakis(tert-butyl)metallo-phthalocyanines: Regioselective Synthesis and Spectral Investigations
por: Iida, Norihito, et al.
Publicado: (2015)

Cannot write session to /tmp/vufind_sessions/sess_mmnvishtapu4ror6a5bs7u3n73