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Liquid-Liquid Extraction of Indium(III) from the HCl Medium by Ionic Liquid A327H(+)Cl(−) and Its Use in a Supported Liquid Membrane System
Ionic liquid A327H(+)Cl(−) was generated by reaction of tertiary amine A327 and HCl, and the liquid-liquid extraction of indium(III) from the HCl medium by this ionic liquid dissolved in Solvesso 100 was investigated. The extraction reaction is exothermic. The numerical analysis of indium distributi...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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MDPI
2020
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7698273/ https://www.ncbi.nlm.nih.gov/pubmed/33182748 http://dx.doi.org/10.3390/molecules25225238 |
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author | Alguacil, Francisco José |
author_facet | Alguacil, Francisco José |
author_sort | Alguacil, Francisco José |
collection | PubMed |
description | Ionic liquid A327H(+)Cl(−) was generated by reaction of tertiary amine A327 and HCl, and the liquid-liquid extraction of indium(III) from the HCl medium by this ionic liquid dissolved in Solvesso 100 was investigated. The extraction reaction is exothermic. The numerical analysis of indium distribution data suggests the formation of A327H(+)InCl(4)(−) in the organic phase. The results derived from indium(III) extraction have been implemented in a supported liquid membrane system. The influence of the stirring speed (600–1200 min(−1)), carrier concentration (2.5–20% v/v) in the membrane phase, and indium concentration (0.01–0.2 g/L) in the feed phase on metal transport have been investigated. |
format | Online Article Text |
id | pubmed-7698273 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-76982732020-11-29 Liquid-Liquid Extraction of Indium(III) from the HCl Medium by Ionic Liquid A327H(+)Cl(−) and Its Use in a Supported Liquid Membrane System Alguacil, Francisco José Molecules Article Ionic liquid A327H(+)Cl(−) was generated by reaction of tertiary amine A327 and HCl, and the liquid-liquid extraction of indium(III) from the HCl medium by this ionic liquid dissolved in Solvesso 100 was investigated. The extraction reaction is exothermic. The numerical analysis of indium distribution data suggests the formation of A327H(+)InCl(4)(−) in the organic phase. The results derived from indium(III) extraction have been implemented in a supported liquid membrane system. The influence of the stirring speed (600–1200 min(−1)), carrier concentration (2.5–20% v/v) in the membrane phase, and indium concentration (0.01–0.2 g/L) in the feed phase on metal transport have been investigated. MDPI 2020-11-10 /pmc/articles/PMC7698273/ /pubmed/33182748 http://dx.doi.org/10.3390/molecules25225238 Text en © 2020 by the author. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Alguacil, Francisco José Liquid-Liquid Extraction of Indium(III) from the HCl Medium by Ionic Liquid A327H(+)Cl(−) and Its Use in a Supported Liquid Membrane System |
title | Liquid-Liquid Extraction of Indium(III) from the HCl Medium by Ionic Liquid A327H(+)Cl(−) and Its Use in a Supported Liquid Membrane System |
title_full | Liquid-Liquid Extraction of Indium(III) from the HCl Medium by Ionic Liquid A327H(+)Cl(−) and Its Use in a Supported Liquid Membrane System |
title_fullStr | Liquid-Liquid Extraction of Indium(III) from the HCl Medium by Ionic Liquid A327H(+)Cl(−) and Its Use in a Supported Liquid Membrane System |
title_full_unstemmed | Liquid-Liquid Extraction of Indium(III) from the HCl Medium by Ionic Liquid A327H(+)Cl(−) and Its Use in a Supported Liquid Membrane System |
title_short | Liquid-Liquid Extraction of Indium(III) from the HCl Medium by Ionic Liquid A327H(+)Cl(−) and Its Use in a Supported Liquid Membrane System |
title_sort | liquid-liquid extraction of indium(iii) from the hcl medium by ionic liquid a327h(+)cl(−) and its use in a supported liquid membrane system |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7698273/ https://www.ncbi.nlm.nih.gov/pubmed/33182748 http://dx.doi.org/10.3390/molecules25225238 |
work_keys_str_mv | AT alguacilfranciscojose liquidliquidextractionofindiumiiifromthehclmediumbyionicliquida327hclanditsuseinasupportedliquidmembranesystem |