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Liquid-Liquid Extraction of Indium(III) from the HCl Medium by Ionic Liquid A327H(+)Cl(−) and Its Use in a Supported Liquid Membrane System

Ionic liquid A327H(+)Cl(−) was generated by reaction of tertiary amine A327 and HCl, and the liquid-liquid extraction of indium(III) from the HCl medium by this ionic liquid dissolved in Solvesso 100 was investigated. The extraction reaction is exothermic. The numerical analysis of indium distributi...

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Autor principal: Alguacil, Francisco José
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7698273/
https://www.ncbi.nlm.nih.gov/pubmed/33182748
http://dx.doi.org/10.3390/molecules25225238
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author Alguacil, Francisco José
author_facet Alguacil, Francisco José
author_sort Alguacil, Francisco José
collection PubMed
description Ionic liquid A327H(+)Cl(−) was generated by reaction of tertiary amine A327 and HCl, and the liquid-liquid extraction of indium(III) from the HCl medium by this ionic liquid dissolved in Solvesso 100 was investigated. The extraction reaction is exothermic. The numerical analysis of indium distribution data suggests the formation of A327H(+)InCl(4)(−) in the organic phase. The results derived from indium(III) extraction have been implemented in a supported liquid membrane system. The influence of the stirring speed (600–1200 min(−1)), carrier concentration (2.5–20% v/v) in the membrane phase, and indium concentration (0.01–0.2 g/L) in the feed phase on metal transport have been investigated.
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spelling pubmed-76982732020-11-29 Liquid-Liquid Extraction of Indium(III) from the HCl Medium by Ionic Liquid A327H(+)Cl(−) and Its Use in a Supported Liquid Membrane System Alguacil, Francisco José Molecules Article Ionic liquid A327H(+)Cl(−) was generated by reaction of tertiary amine A327 and HCl, and the liquid-liquid extraction of indium(III) from the HCl medium by this ionic liquid dissolved in Solvesso 100 was investigated. The extraction reaction is exothermic. The numerical analysis of indium distribution data suggests the formation of A327H(+)InCl(4)(−) in the organic phase. The results derived from indium(III) extraction have been implemented in a supported liquid membrane system. The influence of the stirring speed (600–1200 min(−1)), carrier concentration (2.5–20% v/v) in the membrane phase, and indium concentration (0.01–0.2 g/L) in the feed phase on metal transport have been investigated. MDPI 2020-11-10 /pmc/articles/PMC7698273/ /pubmed/33182748 http://dx.doi.org/10.3390/molecules25225238 Text en © 2020 by the author. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Alguacil, Francisco José
Liquid-Liquid Extraction of Indium(III) from the HCl Medium by Ionic Liquid A327H(+)Cl(−) and Its Use in a Supported Liquid Membrane System
title Liquid-Liquid Extraction of Indium(III) from the HCl Medium by Ionic Liquid A327H(+)Cl(−) and Its Use in a Supported Liquid Membrane System
title_full Liquid-Liquid Extraction of Indium(III) from the HCl Medium by Ionic Liquid A327H(+)Cl(−) and Its Use in a Supported Liquid Membrane System
title_fullStr Liquid-Liquid Extraction of Indium(III) from the HCl Medium by Ionic Liquid A327H(+)Cl(−) and Its Use in a Supported Liquid Membrane System
title_full_unstemmed Liquid-Liquid Extraction of Indium(III) from the HCl Medium by Ionic Liquid A327H(+)Cl(−) and Its Use in a Supported Liquid Membrane System
title_short Liquid-Liquid Extraction of Indium(III) from the HCl Medium by Ionic Liquid A327H(+)Cl(−) and Its Use in a Supported Liquid Membrane System
title_sort liquid-liquid extraction of indium(iii) from the hcl medium by ionic liquid a327h(+)cl(−) and its use in a supported liquid membrane system
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7698273/
https://www.ncbi.nlm.nih.gov/pubmed/33182748
http://dx.doi.org/10.3390/molecules25225238
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