An Approach to Paracyclophane-Based Tetrathiafulvalenes: Synthesis and Characterization of a Pseudo-Geminal [2.2]Paracyclophane 1,3-Dithia-2-Thione

The synthesis of paracyclophane-based tetrathiafulvalene precursors is described in the context of the importance of these compounds in the field of material chemistry. Pseudo-geminal bis(1,3-dithia-2-thione) was synthesized via the corresponding 1,3-dithiol-2-ylium salt. The latter was obtained by...

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Autores principales: Bahrin, Lucian G., Hopf, Henning, Jones, Peter G., Birsa, Mihail L., Sarbu, Laura G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7698277/
https://www.ncbi.nlm.nih.gov/pubmed/33187391
http://dx.doi.org/10.3390/molecules25225262
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author Bahrin, Lucian G.
Hopf, Henning
Jones, Peter G.
Birsa, Mihail L.
Sarbu, Laura G.
author_facet Bahrin, Lucian G.
Hopf, Henning
Jones, Peter G.
Birsa, Mihail L.
Sarbu, Laura G.
author_sort Bahrin, Lucian G.
collection PubMed
description The synthesis of paracyclophane-based tetrathiafulvalene precursors is described in the context of the importance of these compounds in the field of material chemistry. Pseudo-geminal bis(1,3-dithia-2-thione) was synthesized via the corresponding 1,3-dithiol-2-ylium salt. The latter was obtained by a synthetic procedure that involves 4,15-bis(acetyl)[2.2]paracyclophane, a new compound of interest for many researchers.
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spelling pubmed-76982772020-11-29 An Approach to Paracyclophane-Based Tetrathiafulvalenes: Synthesis and Characterization of a Pseudo-Geminal [2.2]Paracyclophane 1,3-Dithia-2-Thione Bahrin, Lucian G. Hopf, Henning Jones, Peter G. Birsa, Mihail L. Sarbu, Laura G. Molecules Article The synthesis of paracyclophane-based tetrathiafulvalene precursors is described in the context of the importance of these compounds in the field of material chemistry. Pseudo-geminal bis(1,3-dithia-2-thione) was synthesized via the corresponding 1,3-dithiol-2-ylium salt. The latter was obtained by a synthetic procedure that involves 4,15-bis(acetyl)[2.2]paracyclophane, a new compound of interest for many researchers. MDPI 2020-11-11 /pmc/articles/PMC7698277/ /pubmed/33187391 http://dx.doi.org/10.3390/molecules25225262 Text en © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Bahrin, Lucian G.
Hopf, Henning
Jones, Peter G.
Birsa, Mihail L.
Sarbu, Laura G.
An Approach to Paracyclophane-Based Tetrathiafulvalenes: Synthesis and Characterization of a Pseudo-Geminal [2.2]Paracyclophane 1,3-Dithia-2-Thione
title An Approach to Paracyclophane-Based Tetrathiafulvalenes: Synthesis and Characterization of a Pseudo-Geminal [2.2]Paracyclophane 1,3-Dithia-2-Thione
title_full An Approach to Paracyclophane-Based Tetrathiafulvalenes: Synthesis and Characterization of a Pseudo-Geminal [2.2]Paracyclophane 1,3-Dithia-2-Thione
title_fullStr An Approach to Paracyclophane-Based Tetrathiafulvalenes: Synthesis and Characterization of a Pseudo-Geminal [2.2]Paracyclophane 1,3-Dithia-2-Thione
title_full_unstemmed An Approach to Paracyclophane-Based Tetrathiafulvalenes: Synthesis and Characterization of a Pseudo-Geminal [2.2]Paracyclophane 1,3-Dithia-2-Thione
title_short An Approach to Paracyclophane-Based Tetrathiafulvalenes: Synthesis and Characterization of a Pseudo-Geminal [2.2]Paracyclophane 1,3-Dithia-2-Thione
title_sort approach to paracyclophane-based tetrathiafulvalenes: synthesis and characterization of a pseudo-geminal [2.2]paracyclophane 1,3-dithia-2-thione
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7698277/
https://www.ncbi.nlm.nih.gov/pubmed/33187391
http://dx.doi.org/10.3390/molecules25225262
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