Intermolecular Hydroaminoalkylation of Propadiene

Intermolecular hydroaminoalkylation reactions of propadiene with selected secondary amines take place in the presence of a 2,6‐bis(phenylamino)pyridinato titanium catalyst. The corresponding products, synthetically useful allylamines, are formed in convincing yields and with high selectivities. In a...

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Autores principales: Kaper, Tobias, Fischer, Malte, Warsitz, Michael, Zimmering, René, Beckhaus, Ruediger, Doye, Sven
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7702142/
https://www.ncbi.nlm.nih.gov/pubmed/32844473
http://dx.doi.org/10.1002/chem.202003484
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author Kaper, Tobias
Fischer, Malte
Warsitz, Michael
Zimmering, René
Beckhaus, Ruediger
Doye, Sven
author_facet Kaper, Tobias
Fischer, Malte
Warsitz, Michael
Zimmering, René
Beckhaus, Ruediger
Doye, Sven
author_sort Kaper, Tobias
collection PubMed
description Intermolecular hydroaminoalkylation reactions of propadiene with selected secondary amines take place in the presence of a 2,6‐bis(phenylamino)pyridinato titanium catalyst. The corresponding products, synthetically useful allylamines, are formed in convincing yields and with high selectivities. In addition, propadiene easily inserts into the titanium‐carbon bond of a titanaaziridine.
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spelling pubmed-77021422020-12-14 Intermolecular Hydroaminoalkylation of Propadiene Kaper, Tobias Fischer, Malte Warsitz, Michael Zimmering, René Beckhaus, Ruediger Doye, Sven Chemistry Communications Intermolecular hydroaminoalkylation reactions of propadiene with selected secondary amines take place in the presence of a 2,6‐bis(phenylamino)pyridinato titanium catalyst. The corresponding products, synthetically useful allylamines, are formed in convincing yields and with high selectivities. In addition, propadiene easily inserts into the titanium‐carbon bond of a titanaaziridine. John Wiley and Sons Inc. 2020-10-01 2020-11-11 /pmc/articles/PMC7702142/ /pubmed/32844473 http://dx.doi.org/10.1002/chem.202003484 Text en © 2020 The Authors. Published by Wiley-VCH GmbH This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc-nd/4.0/ License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.
spellingShingle Communications
Kaper, Tobias
Fischer, Malte
Warsitz, Michael
Zimmering, René
Beckhaus, Ruediger
Doye, Sven
Intermolecular Hydroaminoalkylation of Propadiene
title Intermolecular Hydroaminoalkylation of Propadiene
title_full Intermolecular Hydroaminoalkylation of Propadiene
title_fullStr Intermolecular Hydroaminoalkylation of Propadiene
title_full_unstemmed Intermolecular Hydroaminoalkylation of Propadiene
title_short Intermolecular Hydroaminoalkylation of Propadiene
title_sort intermolecular hydroaminoalkylation of propadiene
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7702142/
https://www.ncbi.nlm.nih.gov/pubmed/32844473
http://dx.doi.org/10.1002/chem.202003484
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AT zimmeringrene intermolecularhydroaminoalkylationofpropadiene
AT beckhausruediger intermolecularhydroaminoalkylationofpropadiene
AT doyesven intermolecularhydroaminoalkylationofpropadiene

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