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Visible-light photoredox-catalyzed C–O bond cleavage of diaryl ethers by acridinium photocatalysts at room temperature

Cleavage of C–O bonds in lignin can afford the renewable aryl sources for fine chemicals. However, the high bond energies of these C–O bonds, especially the 4-O-5-type diaryl ether C–O bonds (~314 kJ/mol) make the cleavage very challenging. Here, we report visible-light photoredox-catalyzed C–O bond...

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Detalles Bibliográficos
Autores principales: Tan, Fang-Fang, He, Xiao-Ya, Tian, Wan-Fa, Li, Yang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7705023/
https://www.ncbi.nlm.nih.gov/pubmed/33257656
http://dx.doi.org/10.1038/s41467-020-19944-x

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