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Black TiO(2) Synthesis by Chemical Reduction Methods for Photocatalysis Applications
Applications of TiO(2) nanomaterials in photocatalysis, batteries, supercapacitors and solar cells, have seen widespread development in recent decades. Nowadays, black TiO(2) have won attention due to enhancing the solar light absorption by the formation of oxygen vacancies and Ti(3+) defects, to pr...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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Frontiers Media S.A.
2020
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7705109/ https://www.ncbi.nlm.nih.gov/pubmed/33282823 http://dx.doi.org/10.3389/fchem.2020.565489 |
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author | Andronic, Luminita Enesca, Alexandru |
author_facet | Andronic, Luminita Enesca, Alexandru |
author_sort | Andronic, Luminita |
collection | PubMed |
description | Applications of TiO(2) nanomaterials in photocatalysis, batteries, supercapacitors and solar cells, have seen widespread development in recent decades. Nowadays, black TiO(2) have won attention due to enhancing the solar light absorption by the formation of oxygen vacancies and Ti(3+) defects, to promote the separation of photo-generated charge carriers leading to the improvement of the photocatalytic performance in H(2) production and pollutants degradation. The enhanced photocatalytic activity of black TiO(2) is also due to a lattice disorder on the surface and the presence of oxygen vacancies, Ti(3+) ions, Ti-OH and Ti-H groups. Enhancing the optical absorption characteristics of TiO(2) and change of energy level and band-gap of materials have been successfully demonstrated to improve their photocatalytic activities, especially for black TiO(2) nanoparticles, which promote visible light absorption. The current review focuses on the investigation of the chemical reduction synthetic route for black TiO(2) nanomaterials, and their proposed association with green applications such as photodegradation of organic pollutants and photocatalytic water splitting. The synthesis methods of black TiO(2) involves the changes from Ti(4+) to Ti(3+) state, into different strategies: (1) The use of highly active hydrogen species such as H(2), H(2)/Ar or H(2)/N(2) gases, and metal hydrides (NaBH(4), CaH(2)), (2) the reduction by active metals such as aluminum, magnesium and zinc, and (3) organic molecules such as imidazole and ascorbic acid. |
format | Online Article Text |
id | pubmed-7705109 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | Frontiers Media S.A. |
record_format | MEDLINE/PubMed |
spelling | pubmed-77051092020-12-03 Black TiO(2) Synthesis by Chemical Reduction Methods for Photocatalysis Applications Andronic, Luminita Enesca, Alexandru Front Chem Chemistry Applications of TiO(2) nanomaterials in photocatalysis, batteries, supercapacitors and solar cells, have seen widespread development in recent decades. Nowadays, black TiO(2) have won attention due to enhancing the solar light absorption by the formation of oxygen vacancies and Ti(3+) defects, to promote the separation of photo-generated charge carriers leading to the improvement of the photocatalytic performance in H(2) production and pollutants degradation. The enhanced photocatalytic activity of black TiO(2) is also due to a lattice disorder on the surface and the presence of oxygen vacancies, Ti(3+) ions, Ti-OH and Ti-H groups. Enhancing the optical absorption characteristics of TiO(2) and change of energy level and band-gap of materials have been successfully demonstrated to improve their photocatalytic activities, especially for black TiO(2) nanoparticles, which promote visible light absorption. The current review focuses on the investigation of the chemical reduction synthetic route for black TiO(2) nanomaterials, and their proposed association with green applications such as photodegradation of organic pollutants and photocatalytic water splitting. The synthesis methods of black TiO(2) involves the changes from Ti(4+) to Ti(3+) state, into different strategies: (1) The use of highly active hydrogen species such as H(2), H(2)/Ar or H(2)/N(2) gases, and metal hydrides (NaBH(4), CaH(2)), (2) the reduction by active metals such as aluminum, magnesium and zinc, and (3) organic molecules such as imidazole and ascorbic acid. Frontiers Media S.A. 2020-11-17 /pmc/articles/PMC7705109/ /pubmed/33282823 http://dx.doi.org/10.3389/fchem.2020.565489 Text en Copyright © 2020 Andronic and Enesca. http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms. |
spellingShingle | Chemistry Andronic, Luminita Enesca, Alexandru Black TiO(2) Synthesis by Chemical Reduction Methods for Photocatalysis Applications |
title | Black TiO(2) Synthesis by Chemical Reduction Methods for Photocatalysis Applications |
title_full | Black TiO(2) Synthesis by Chemical Reduction Methods for Photocatalysis Applications |
title_fullStr | Black TiO(2) Synthesis by Chemical Reduction Methods for Photocatalysis Applications |
title_full_unstemmed | Black TiO(2) Synthesis by Chemical Reduction Methods for Photocatalysis Applications |
title_short | Black TiO(2) Synthesis by Chemical Reduction Methods for Photocatalysis Applications |
title_sort | black tio(2) synthesis by chemical reduction methods for photocatalysis applications |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7705109/ https://www.ncbi.nlm.nih.gov/pubmed/33282823 http://dx.doi.org/10.3389/fchem.2020.565489 |
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