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Hybrid Li/Na Ion Batteries: Temperature-Induced Reactivity of Three-Layered Oxide (P3-Na(2/3)Ni(1/3)Mg(1/6)Mn(1/2)O(2)) Toward Lithium Ionic Liquid Electrolytes
Hybrid metal ion batteries are perceived as competitive alternatives to lithium ion batteries because they provide better balance between energy/power density, battery cost, and environmental requirements. However, their cycling stability and high-temperature storage performance are still far from t...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Frontiers Media S.A.
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7714996/ https://www.ncbi.nlm.nih.gov/pubmed/33330392 http://dx.doi.org/10.3389/fchem.2020.600140 |
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author | Kalapsazova, Mariya Kostov, Krassimir Zhecheva, Ekaterina Stoyanova, Radostina |
author_facet | Kalapsazova, Mariya Kostov, Krassimir Zhecheva, Ekaterina Stoyanova, Radostina |
author_sort | Kalapsazova, Mariya |
collection | PubMed |
description | Hybrid metal ion batteries are perceived as competitive alternatives to lithium ion batteries because they provide better balance between energy/power density, battery cost, and environmental requirements. However, their cycling stability and high-temperature storage performance are still far from the desired. Herein, we first examine the temperature-induced reactivity of three-layered oxide, P3-Na(2/3)Ni(1/3)Mg(1/6)Mn(1/2)O(2), toward lithium ionic liquid electrolyte upon cycling in hybrid Li/Na ion cells. Through ex situ X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) analyses, the structural and surface changes in P3-Na(2/3)Ni(1/3)Mg(1/6)Mn(1/2)O(2) are monitored and discussed. Understanding the relevant changes occurring during dual Li(+) and Na(+) intercalation into P3-Na(2/3)Ni(1/3)Mg(1/6)Mn(1/2)O(2) is of crucial importance to enhance the overall performance of hybrid Li/Na ion batteries at elevated temperatures. |
format | Online Article Text |
id | pubmed-7714996 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | Frontiers Media S.A. |
record_format | MEDLINE/PubMed |
spelling | pubmed-77149962020-12-15 Hybrid Li/Na Ion Batteries: Temperature-Induced Reactivity of Three-Layered Oxide (P3-Na(2/3)Ni(1/3)Mg(1/6)Mn(1/2)O(2)) Toward Lithium Ionic Liquid Electrolytes Kalapsazova, Mariya Kostov, Krassimir Zhecheva, Ekaterina Stoyanova, Radostina Front Chem Chemistry Hybrid metal ion batteries are perceived as competitive alternatives to lithium ion batteries because they provide better balance between energy/power density, battery cost, and environmental requirements. However, their cycling stability and high-temperature storage performance are still far from the desired. Herein, we first examine the temperature-induced reactivity of three-layered oxide, P3-Na(2/3)Ni(1/3)Mg(1/6)Mn(1/2)O(2), toward lithium ionic liquid electrolyte upon cycling in hybrid Li/Na ion cells. Through ex situ X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) analyses, the structural and surface changes in P3-Na(2/3)Ni(1/3)Mg(1/6)Mn(1/2)O(2) are monitored and discussed. Understanding the relevant changes occurring during dual Li(+) and Na(+) intercalation into P3-Na(2/3)Ni(1/3)Mg(1/6)Mn(1/2)O(2) is of crucial importance to enhance the overall performance of hybrid Li/Na ion batteries at elevated temperatures. Frontiers Media S.A. 2020-11-20 /pmc/articles/PMC7714996/ /pubmed/33330392 http://dx.doi.org/10.3389/fchem.2020.600140 Text en Copyright © 2020 Kalapsazova, Kostov, Zhecheva and Stoyanova. http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms. |
spellingShingle | Chemistry Kalapsazova, Mariya Kostov, Krassimir Zhecheva, Ekaterina Stoyanova, Radostina Hybrid Li/Na Ion Batteries: Temperature-Induced Reactivity of Three-Layered Oxide (P3-Na(2/3)Ni(1/3)Mg(1/6)Mn(1/2)O(2)) Toward Lithium Ionic Liquid Electrolytes |
title | Hybrid Li/Na Ion Batteries: Temperature-Induced Reactivity of Three-Layered Oxide (P3-Na(2/3)Ni(1/3)Mg(1/6)Mn(1/2)O(2)) Toward Lithium Ionic Liquid Electrolytes |
title_full | Hybrid Li/Na Ion Batteries: Temperature-Induced Reactivity of Three-Layered Oxide (P3-Na(2/3)Ni(1/3)Mg(1/6)Mn(1/2)O(2)) Toward Lithium Ionic Liquid Electrolytes |
title_fullStr | Hybrid Li/Na Ion Batteries: Temperature-Induced Reactivity of Three-Layered Oxide (P3-Na(2/3)Ni(1/3)Mg(1/6)Mn(1/2)O(2)) Toward Lithium Ionic Liquid Electrolytes |
title_full_unstemmed | Hybrid Li/Na Ion Batteries: Temperature-Induced Reactivity of Three-Layered Oxide (P3-Na(2/3)Ni(1/3)Mg(1/6)Mn(1/2)O(2)) Toward Lithium Ionic Liquid Electrolytes |
title_short | Hybrid Li/Na Ion Batteries: Temperature-Induced Reactivity of Three-Layered Oxide (P3-Na(2/3)Ni(1/3)Mg(1/6)Mn(1/2)O(2)) Toward Lithium Ionic Liquid Electrolytes |
title_sort | hybrid li/na ion batteries: temperature-induced reactivity of three-layered oxide (p3-na(2/3)ni(1/3)mg(1/6)mn(1/2)o(2)) toward lithium ionic liquid electrolytes |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7714996/ https://www.ncbi.nlm.nih.gov/pubmed/33330392 http://dx.doi.org/10.3389/fchem.2020.600140 |
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