Anionic polyacrylamide influence on the lead(II) ion accumulation in soil – the study on montmorillonite

PURPOSE: Polymeric substances, as soil conditioners, limit the erosion process as well as improve the soil structure. The same macromolecular compounds may influence the heavy metal accumulation in soil environment. The main aim of this study was investigation of anionic polyacrylamide (AN PAM) effect on the lead(II) ion sorption on the montmorillonite surface. The effects of Pb(II) ion concentration, sequence of heavy metal and anionic polymer addition into the system as well as anionic group content in the PAM macromolecules were also studied. MATERIALS AND METHODS: The study was performed on montmorillonite (clay mineral). Two types of polymers were used: AN PAM 5% and AN PAM 30% containing 5% and 30% of carboxylic groups, respectively. The adsorbed amounts of Pb(II) ions or AN PAM on the solid were determined spectrophotometrically. Electrokinetic properties of the examined systems were established using potentiometric titration and microelectrophoresis method. The montmorillonite aggregation without and with selected substances was described based on the sedimentation study. RESULTS: At pH 5 the Pb(II) adsorbed amount on montmorillonite equaled 0.05 mg/m(2) (for the initial concentration 10 ppm). Anionic polyacrylamide increased this value significantly (it was 0.11 mg/m(2) with AN PAM 5% and 0.11 mg/m(2) with AN PAM 30%). The lead(II) ions presence causes a slight increase of the anionic PAM adsorption on the montmorillonite surface. For example, for the initial polymer concentration 100 ppm, the AN PAM 5% adsorbed amount without Pb(II) equaled 0.49 mg/m(2), whereas with Pb(II) – 0.57 mg/m(2). What is more, anionic polyacrylamide and lead(II) ions affected electrokinetic properties and stability of the montmorillonite suspension. CONCLUSIONS: Anionic polyacrylamide makes the Pb(II) accumulation on the montmorillonite surface larger and, as a consequence, reduces the Pb(II) availability to organisms. Therefore, this macromolecular compound can certainly be used to remediate soils contaminated with heavy metals.