Controlled decomposition of SF(6) by electrochemical reduction

The electroreduction of SF(6) is shown at ambient temperature in acetonitrile using an array of platinum microelectrodes to improve the electrical detection. Its half reduction potential occurs at −2.17 V vs Fc(+)/Fc. The exact number of electrons for the full consumption of sulfur hexafluoride was...

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Detalles Bibliográficos
Autores principales: Bouvet, Sébastien, Pégot, Bruce, Sengmany, Stéphane, Le Gall, Erwan, Léonel, Eric, Goncalves, Anne-Marie, Magnier, Emmanuel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2020
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7722628/
https://www.ncbi.nlm.nih.gov/pubmed/33335602
http://dx.doi.org/10.3762/bjoc.16.244
Descripción
Sumario:The electroreduction of SF(6) is shown at ambient temperature in acetonitrile using an array of platinum microelectrodes to improve the electrical detection. Its half reduction potential occurs at −2.17 V vs Fc(+)/Fc. The exact number of electrons for the full consumption of sulfur hexafluoride was determined and this gas further quantitatively transformed into environmentally benign fluoride anion and sulfur by electrochemical reduction.

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