Controlled decomposition of SF(6) by electrochemical reduction

The electroreduction of SF(6) is shown at ambient temperature in acetonitrile using an array of platinum microelectrodes to improve the electrical detection. Its half reduction potential occurs at −2.17 V vs Fc(+)/Fc. The exact number of electrons for the full consumption of sulfur hexafluoride was...

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Autores principales: Bouvet, Sébastien, Pégot, Bruce, Sengmany, Stéphane, Le Gall, Erwan, Léonel, Eric, Goncalves, Anne-Marie, Magnier, Emmanuel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2020
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7722628/
https://www.ncbi.nlm.nih.gov/pubmed/33335602
http://dx.doi.org/10.3762/bjoc.16.244
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author Bouvet, Sébastien
Pégot, Bruce
Sengmany, Stéphane
Le Gall, Erwan
Léonel, Eric
Goncalves, Anne-Marie
Magnier, Emmanuel
author_facet Bouvet, Sébastien
Pégot, Bruce
Sengmany, Stéphane
Le Gall, Erwan
Léonel, Eric
Goncalves, Anne-Marie
Magnier, Emmanuel
author_sort Bouvet, Sébastien
collection PubMed
description The electroreduction of SF(6) is shown at ambient temperature in acetonitrile using an array of platinum microelectrodes to improve the electrical detection. Its half reduction potential occurs at −2.17 V vs Fc(+)/Fc. The exact number of electrons for the full consumption of sulfur hexafluoride was determined and this gas further quantitatively transformed into environmentally benign fluoride anion and sulfur by electrochemical reduction.
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spelling pubmed-77226282020-12-16 Controlled decomposition of SF(6) by electrochemical reduction Bouvet, Sébastien Pégot, Bruce Sengmany, Stéphane Le Gall, Erwan Léonel, Eric Goncalves, Anne-Marie Magnier, Emmanuel Beilstein J Org Chem Full Research Paper The electroreduction of SF(6) is shown at ambient temperature in acetonitrile using an array of platinum microelectrodes to improve the electrical detection. Its half reduction potential occurs at −2.17 V vs Fc(+)/Fc. The exact number of electrons for the full consumption of sulfur hexafluoride was determined and this gas further quantitatively transformed into environmentally benign fluoride anion and sulfur by electrochemical reduction. Beilstein-Institut 2020-12-01 /pmc/articles/PMC7722628/ /pubmed/33335602 http://dx.doi.org/10.3762/bjoc.16.244 Text en Copyright © 2020, Bouvet et al. https://creativecommons.org/licenses/by/4.0https://www.beilstein-journals.org/bjoc/terms/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0). Please note that the reuse, redistribution and reproduction in particular requires that the author(s) and source are credited and that individual graphics may be subject to special legal provisions. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms/terms)
spellingShingle Full Research Paper
Bouvet, Sébastien
Pégot, Bruce
Sengmany, Stéphane
Le Gall, Erwan
Léonel, Eric
Goncalves, Anne-Marie
Magnier, Emmanuel
Controlled decomposition of SF(6) by electrochemical reduction
title Controlled decomposition of SF(6) by electrochemical reduction
title_full Controlled decomposition of SF(6) by electrochemical reduction
title_fullStr Controlled decomposition of SF(6) by electrochemical reduction
title_full_unstemmed Controlled decomposition of SF(6) by electrochemical reduction
title_short Controlled decomposition of SF(6) by electrochemical reduction
title_sort controlled decomposition of sf(6) by electrochemical reduction
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7722628/
https://www.ncbi.nlm.nih.gov/pubmed/33335602
http://dx.doi.org/10.3762/bjoc.16.244
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